期待已久的小刚性对称三内酰胺的合成和自组装。
The long-awaited synthesis and self-assembly of a small rigid -symmetric trilactam.
机构信息
Centre for Analysis and Synthesis, Department of Chemistry, Lund University, SE-221 00 Lund, Sweden.
Mulliken Center for Theoretical Chemistry, Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, 53115 Bonn, Germany.
出版信息
Chem Commun (Camb). 2022 Mar 18;58(23):3751-3754. doi: 10.1039/d2cc00345g.
The challenging synthesis of a fused -symmetric trilactam (1) was executed in racemic and enantiomerically pure form. The rigidity, symmetry and high density of hydrogen bonding motifs make 1 an attractive candidate for self-assembly study, which revealed different hydrogen bond patterns in the crystals of -1- and (+)-()-1.
具有融合对称结构的三环酰胺（1）的合成极具挑战性，我们以外消旋和对映纯两种形式进行了合成。1 的刚性、对称性和高密度氢键模式使其成为自组装研究的理想候选物，其晶体中的（-）-1 和（+）-()-1 表现出不同的氢键模式。
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