Discovery of Kinetic Effect in a Valence Tautomeric Cobalt-Dioxolene Complex.
作者信息
Sun Xiao-Peng, Tang Zheng, Li Jiajia, Ma Pengtao, Yao Zi-Shuo, Wang Jingping, Niu Jingyang, Tao Jun
机构信息
Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China.
Key Laboratory of Cluster Science of the Ministry of Education, School of Chemistry and Chemical Engineering, Liangxiang Campus, Beijing Institute of Technology, Beijing 102488, China.
出版信息
Inorg Chem. 2022 Mar 14;61(10):4240-4245. doi: 10.1021/acs.inorgchem.1c03898. Epub 2022 Mar 2.
Two isostructural valence tautomeric (VT) complexes with different critical temperatures were prepared and fully investigated through a series of magnetic, structural, spectral, and differential scanning calorimetry evidence. The kinetic effect in the VT complex was observed for the first time through scan-rate-dependent studies and further validated by annealing tests.
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