Phosphorus transformation during the carbonaceous skeleton assisted thermal hydrolysis of sludge.

On the basis of the carbonaceous skeleton assisted thermal hydrolysis that we proposed to achieve efficient sludge dewatering, this work further explored phosphorus (P) transformation in the process. The results showed that during independent thermal hydrolysis in the temperature range of 120-240 °C, organic-P was first decomposed into soluble-P and particulate-P in liquid, and then combined with Ca, Fe, and Al to form more apatite-P (AP) and less non-apatite inorganic-P (NAIP). When the skeleton assisted the sludge thermal hydrolysis, the turning point of the hydrolysis temperature would reduce from 180 °C to 150 °C, at which the liquid-P began to decrease and the organic-P generally decomposed. Moreover, the increment in the content of AP halved while that of NAIP doubled compared to that in the process without the carbonaceous skeleton. These effects come from the exogenous components introduced by adding the skeleton, which were different from the sludge. Compared with the P-rich compound and metal elements that tend to bond with phosphate introduced by the skeleton, hemicellulose as a main organic component played a leading role in the different P transformations of AP and NAIP. The hemicellulose slightly increased the acidity of sludge products, thereby inhibiting AP production and promoting the production of recyclable NAIP. Overall, the carbonaceous skeleton assisted thermal hydrolysis was beneficial for P recovery with a very low filtrate loss rate.