Recent advances in borenium catalysis.

Borenium ions are strong Lewis acids because of the positive charge on boron. While their high reactivity had long restricted their role in organic synthesis to stoichiometric reagents, in the past ten years the introduction of suitable supporting ligands, such as N-heterocyclic carbenes, has enabled them to function as competent catalysts for various organic transformations involving the activation of strong covalent bonds, such as H-H, Si-H, B-H, C-H and C-C bonds. This review provides an overview of the recent advances in borenium-catalysed reactions with emphasis on catalyst synthesis, methodology development and mechanistic insight.