双（2-吡啶硫基）甲基氢化锌的合成以及一氧化碳的催化硅氢化和硼氢化反应
Synthesis of bis(2-pyridylthio)methyl zinc hydride and catalytic hydrosilylation and hydroboration of CO.
作者信息
Shlian Daniel G, Amemiya Erika, Parkin Gerard
机构信息
Department of Chemistry, Columbia University, New York, NY 10027, USA.
出版信息
Chem Commun (Camb). 2022 Mar 29;58(26):4188-4191. doi: 10.1039/d1cc06963b.
PMID:35266933
Abstract
The reactions of bis(2-pyridylthio)methane with MeZn and Zn[N(SiMe)] afford [Bptm]ZnMe and [Bptm]ZnN(SiMe), thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as a catalyst for the reduction of CO and other carbonyl compounds hydrosilylation and hydroboration.
摘要
双（2-吡啶硫基）甲烷与甲基锌和Zn[N(SiMe)]反应生成[Bptm]ZnMe和[Bptm]ZnN(SiMe)，从而能够制备多种其他的[Bptm]ZnX衍生物，包括氢化锌配合物[Bptm]ZnH，它可作为还原CO和其他羰基化合物的硅氢化和硼氢化反应的催化剂。
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