Dai Ruijie, Huang Tengzuo, Zhou Weijie, Yang Jinpeng, Zhang Hua, Yu Fayin, Chen Anran, Wang Feng, Zhang Jin, Sun Tao, Zhang Longzhou
International Joint Research Center for Optoelectronic and Energy Materials, Yunnan University, Kunming 650091, China.
School of Materials and Energy, Yunnan University, Kunming 650091, China.
Molecules. 2022 Mar 5;27(5):1710. doi: 10.3390/molecules27051710.
Reducing the surface reflectivity of silicon substrates is essential for preparing high-performance Si-based solar cells. We synthesized pyramid-nanowire-structured Si (Si-PNWs) anti-reflection substrates, which have excellent light-trapping ability (<4% reflectance). Furthermore, diethyl phthalate (DEP), a water-insoluble phthalic acid ester, was applied to optimize the Si-PNWs/PEDOT:PSS interface; the photoelectric conversion efficiency of heterojunction solar cells was shown to increase from 9.82% to 13.48%. We performed a detailed examination of the shape and optical characteristics of Si-PNWs, as well as associated photoelectric performance tests, to investigate the origin of performance improvements in Si-PNWs/PEDOT:PSS heterojunction solar cells (HSCs).
降低硅衬底的表面反射率对于制备高性能硅基太阳能电池至关重要。我们合成了具有优异光捕获能力(反射率<4%)的金字塔-纳米线结构硅(Si-PNWs)抗反射衬底。此外,应用了邻苯二甲酸二乙酯(DEP),一种水不溶性邻苯二甲酸酯,来优化Si-PNWs/PEDOT:PSS界面;结果表明,异质结太阳能电池的光电转换效率从9.82%提高到了13.48%。我们对Si-PNWs的形状和光学特性进行了详细研究,并进行了相关的光电性能测试,以探究Si-PNWs/PEDOT:PSS异质结太阳能电池(HSCs)性能提升的根源。