Wu Han, Xie Yimei, Ma Yanan, Zhang Binbin, Xia Bin, Zhang Pengxiang, Qian Wei, He Daping, Zhang Xin, Li Bao-Wen, Nan Ce-Wen
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Center of Smart Materials and Devices, Wuhan University of Technology, Wuhan, 430070, P. R. China.
Hubei Engineering Research Center of RF-Microwave Technology and Application, Wuhan University of Technology, Wuhan, 430070, P. R. China.
Small. 2022 Apr;18(16):e2107087. doi: 10.1002/smll.202107087. Epub 2022 Mar 10.
MXenes have exhibited potential for application in flexible devices owing to their remarkable electronic, optical, and mechanical properties. Printing strategies have emerged as a facile route for additive manufacturing of MXene-based devices, which relies on the rational design of functional inks with appropriate rheological properties. Herein, aqueous MXene/xanthan gum hybrid inks with tunable viscosity, excellent printability, and long-term stability are designed. Screen-printed flexible MXene films using such hybrid inks exhibit a high conductivity up to 4.8 × 10 S m , which is suitable to construct multifunctional devices mainly including electromagnetic shielding, Joule heaters, and piezoresistive sensors. The average electromagnetic interference (EMI) shielding value can reach to 40.1 dB. In the Joule heater, the heating rate of printed MXene film can reach 20 °C s under a driving voltage of 4 V, with a highest steady-state temperature of 130.8 °C. An MXene-based piezoresistive sensor prepared by the printing interdigital electrode also presents good sensing performance with a short response time of 130 ms and wide pressure region up to 30 kPa. As a result, screen-printed MXene film exhibits reinforced multifunctional performance, which is promising for application in the next-generation of intelligent and wearable devices.
由于其卓越的电子、光学和机械性能,MXenes在柔性器件应用方面展现出潜力。印刷策略已成为基于MXene的器件增材制造的便捷途径,这依赖于对具有适当流变学性质的功能墨水进行合理设计。在此,设计了具有可调粘度、优异可印刷性和长期稳定性的水性MXene/黄原胶混合墨水。使用这种混合墨水丝网印刷的柔性MXene薄膜表现出高达4.8×10 S m的高电导率,适用于构建主要包括电磁屏蔽、焦耳加热器和压阻传感器的多功能器件。平均电磁干扰(EMI)屏蔽值可达40.1 dB。在焦耳加热器中,印刷的MXene薄膜在4 V驱动电压下的加热速率可达20 °C s,最高稳态温度为130.8 °C。通过印刷叉指电极制备的基于MXene的压阻传感器也具有良好的传感性能,响应时间短至130 ms,压力范围宽至30 kPa。因此,丝网印刷的MXene薄膜表现出增强的多功能性能,有望应用于下一代智能和可穿戴设备。