School of Chemical Engineering, Xiangtan University, Xiangtan 411105, PR China.
School of Chemical Engineering, Xiangtan University, Xiangtan 411105, PR China.
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Jun 5;274:121106. doi: 10.1016/j.saa.2022.121106. Epub 2022 Mar 4.
The dielectric characteristics in the terahertz region contribute to a revealing insight into the material components and provide intermolecular information. The dielectric properties of adulterated honey, described as the real and imaginary parts of the complex dielectric constant (Re[ε] and Im[ε]), were obtained from 0.3 to 1.5 THz. The relationship between invert syrup proportions and complex dielectric constants at different frequencies implied the possibility of using the dielectric property as an indicator of honey authenticity. The selected effective dielectric variables of Re[ε] and Im[ε] and their combination were chosen by stability competitive adaptive reweighted sampling (SCARS) algorithm and then used to establish PLS models. The accuracy and uncertainty result revealed SCARS-PLS model based on the combination of Re[ε] and Im[ε] is the best model relatively. These findings indicated the potential utility of this rapid, non-destructive, and on-site method for authenticity verification.
太赫兹区域的介电特性有助于深入了解材料成分,并提供分子间信息。掺杂蜂蜜的介电特性,描述为复介电常数的实部和虚部(Re[ε]和 Im[ε]),是从 0.3 到 1.5 THz 获得的。反糖浆比例与不同频率下复介电常数之间的关系表明,介电特性可能成为蜂蜜真实性的一个指标。通过稳定性竞争自适应重加权采样(SCARS)算法选择 Re[ε]和 Im[ε]的有效介电变量及其组合,然后用于建立 PLS 模型。准确性和不确定性结果表明,基于 Re[ε]和 Im[ε]组合的 SCARS-PLS 模型相对是最好的模型。这些发现表明,这种快速、无损、现场的方法在真实性验证方面具有潜在的应用价值。