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关于胍胶压裂液在低渗透页岩储层中高压砂悬浮及吸附性能的实验研究:因素分析与机理揭示。

Experimental investigation on the high-pressure sand suspension and adsorption capacity of guar gum fracturing fluid in low-permeability shale reservoirs: factor analysis and mechanism disclosure.

机构信息

College of Science, Heilongjiang Bayi Agricultural University, Daqing, 113001, China.

College of Petroleum Engineering, School of Science, China University of Petroleum (East China), Qingdao, 266580, China.

出版信息

Environ Sci Pollut Res Int. 2022 Jul;29(35):53050-53062. doi: 10.1007/s11356-022-19663-4. Epub 2022 Mar 12.

Abstract

Guar fracturing technology has been considered as a kind of popular EOR technology, but the weak static suspension capacity becomes a challenge due to the poor temperature resistance and stability of guar fracturing fluid. The main goal of this investigation is to explore the effect of different factors on the high-pressure static sand suspension of guar gum fracturing fluid by a synthetic efficient nano-ZrO cross-linker. In particular, a mechanism of static suspended sand of nano-ZrO cross-linker is analyzed by microscopic simulation. The adsorption performance of guar fracturing fluid on the shale surface is also studied for analyzing the environmental pollution and damage of guar gum fracturing fluid to shale reservoirs after cross-linking in this investigation. The results obtained that the inclusion of a small content of nano-ZrO cross-linker (0.4%) leads to an apparent increase of fracturing fluid viscosity and decrease in the falling quality of gravel (104 mPa·s and 0.3 g) compared to the classical cross-linker (63 mPa·s and 3.5 g). The lower adsorption capacity of guar fracturing fluid containing nano-ZrO cross-linker on the shale surface means that it has a weaker pollution ability to the shale reservoir than the commercially available cross-linker. Meanwhile, the grid structure density formed by nano-cross-linker and guar gum is considered to be the key factor to significantly change the suspended sand capacity. The investigation of nano-cross-linker cannot only provide necessary theoretical technology and data support for the stability of water-based fracturing fluid, efficient sand carrying, and the development of water-based fracturing technology, but also effectively protect the underground shale reservoir.

摘要

胍胶压裂技术已被认为是一种流行的 EOR 技术,但由于胍胶压裂液的耐温性和稳定性差,其静态悬浮能力较弱,成为一个挑战。本研究的主要目的是通过合成高效的纳米 ZrO 交联剂来探索不同因素对胍胶压裂液高压静态砂悬浮的影响。特别是通过微观模拟分析了纳米 ZrO 交联剂静态悬浮砂的机理。本研究还研究了胍胶压裂液在页岩表面的吸附性能,以分析交联后胍胶压裂液对页岩储层的环境污染和损害。结果表明,加入少量纳米 ZrO 交联剂(0.4%)可使压裂液粘度明显增加,砾石下落质量明显降低(104 mPa·s 和 0.3 g),而经典交联剂(63 mPa·s 和 3.5 g)。含纳米 ZrO 交联剂的胍胶压裂液在页岩表面的吸附容量较低,意味着它对页岩储层的污染能力比市售交联剂弱。同时,纳米交联剂和胍胶形成的网格结构密度被认为是显著改变携砂能力的关键因素。对纳米交联剂的研究不仅可为水基压裂液的稳定性、高效携砂和水基压裂技术的发展提供必要的理论技术和数据支持,而且还能有效地保护地下页岩储层。

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