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利用硫铝酸钙水泥基支撑剂控制煤层气压裂中煤粉的研究

Investigation on Pulverized Coal Control Using Calcium Sulfoaluminate Cementitious Proppants in Coalbed Methane Fracturing.

作者信息

Li Dongyuan, Luo Pingya, Peng Xiaojun, Zhang Bojian, Fu Wanchun, Zou Tao, Fu Li, Xie Gang

机构信息

State Key Laboratory of Oil & Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China.

Wuhuan Engineering Co., Ltd., Wuhan, Hubei 430223, China.

出版信息

ACS Omega. 2022 Feb 23;7(9):8036-8045. doi: 10.1021/acsomega.1c07185. eCollection 2022 Mar 8.

Abstract

Coalbed methane is a type of high-quality clean energy. The development of coalbed methane helps protect the living environment of humans and solves the safety problems in coal mining. However, a large amount of pulverized coal is generated after coalbed methane fracturing, which reduces the production of coalbed methane. Reduction of pulverized coal generation and prevention of pulverized coal migration are important for the development of coalbed methane. This study innovatively mixed calcium sulfoaluminate particles and sand to create a new fracturing proppant. The new proppant was carried by the fracturing fluid into the formation cracks and cured to form a permeable cement stone with a certain compressive strength and permeability at formation temperature and pressure. The permeability and compressive strength of the permeable cement stone were measured at different curing temperatures. Results showed that when the compressive strength of the permeable cement stone was 5.46 MPa, the gas and water permeabilities could reach 2.06 and 0.57 D, respectively. The pore diameter distribution was measured with the semi-permeable diaphragm method. The distribution curve was bimodal, and the range of the variation in pore size was 0.6-300 μm. Blocked pulverized coal size was determined using the seepage theory of particles in porous media and verified through a pulverized coal control experiment. Pulverized coal with a diameter larger than 7.67 μm was blocked by the permeable cement stone. The efficiency of the permeable cement stone in controlling pulverized coal could reach 96%. This study proved that calcium sulfoaluminate cementitious proppants can fix pulverized coal and prevent its migration. It also provided the compressive strength of propping fractures and the high permeability needed for drainage under formation conditions.

摘要

煤层气是一种优质清洁能源。煤层气的开发有助于保护人类生存环境,解决煤矿开采中的安全问题。然而,煤层气压裂后会产生大量煤粉,降低了煤层气产量。减少煤粉产生和防止煤粉运移对煤层气开发至关重要。本研究创新性地将硫铝酸钙颗粒与砂子混合,制备出一种新型压裂支撑剂。新型支撑剂由压裂液携带进入地层裂缝,在地层温度和压力下固化形成具有一定抗压强度和渗透率的可渗透水泥石。在不同养护温度下测定了可渗透水泥石的渗透率和抗压强度。结果表明,当可渗透水泥石的抗压强度为5.46MPa时,气体渗透率和水渗透率分别可达2.06D和0.57D。采用半透膜法测定了孔径分布。分布曲线为双峰型,孔径变化范围为0.6 - 300μm。利用多孔介质中颗粒渗流理论确定了封堵煤粉粒径,并通过煤粉控制实验进行了验证。直径大于7.67μm的煤粉被可渗透水泥石封堵。可渗透水泥石控制煤粉的效率可达96%。本研究证明硫铝酸钙胶凝支撑剂能够固定煤粉并防止其运移。同时也提供了支撑裂缝所需的抗压强度和地层条件下排水所需的高渗透率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c3bf/8908534/fa75d622bb32/ao1c07185_0002.jpg

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