Sponge-like porous manganese(II, III) oxide as a coating for solvent-assisted solid-phase microextraction of polycyclic aromatic hydrocarbons followed by gas chromatography-mass spectrometry.

A nanostructure sponge-like porous manganese(II, III) oxide was synthesized and applied as a new fiber coating for solvent-assisted solid-phase microextraction. The synthesized material was characterized via Fourier-transform infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, and N adsorption/desorption techniques. To investigate the extraction performance of the prepared material, direct immersion solid-phase microextraction followed by gas chromatography-mass spectrometry was used for the determination of the selected polycyclic aromatic hydrocarbons in wastewater samples. Three polycyclic aromatic hydrocarbons including 1-methylnaphthalene, anthracene, and pyrene were selected as model analytes. To maximize the sensitivity of the method, key experimental factors affecting the extraction efficiency of the analytes such as ionic strength, extraction solvent, stirring rate, extraction temperature and time, and desorption temperature and time were optimized. The applicability of the new coating material for the extraction of the selected analytes from wastewater samples was evaluated. Under the optimum conditions, detection limits between 0.7 and 1.5 ng L were obtained for the model analytes. The linear dynamic range was 5.0-3.0 × 10 ng L for all the analytes. Relative standard deviations were between 2 and 11%. In the case of real sample analysis, the extraction recoveries of the analytes were obtained in the range of 77-111%.