Zhang Yufeng, Fang Jinjie, Zhang Lipeng, Wei Dong, Zhu Wei, Zhuang Zhongbin
State Key Lab of Organic-Inorganic Composites and Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Beijing Key Laboratory of Energy Environmental Catalysis, Beijing University of Chemical Technology, Beijing 100029, China.
Chem Commun (Camb). 2022 Apr 5;58(28):4488-4491. doi: 10.1039/d2cc00956k.
Amorphous Pd-P metal-metalloid alloy nanoparticles showed a higher electrochemical ethanol oxidation reaction performance than crystalline Pd nanoparticles. The high performance was attributed to the rich defective coordination unsaturated sites and the P alloying, which enhanced the OH adsorption.
非晶态钯-磷金属-类金属合金纳米颗粒表现出比晶态钯纳米颗粒更高的电化学乙醇氧化反应性能。这种高性能归因于丰富的缺陷配位不饱和位点和磷合金化，它们增强了羟基吸附。
