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含叶提取物的盐酸环境中低碳钢的缓蚀作用

Corrosion Inhibition of Mild Steel in Hydrochloric Acid Environments Containing Leaf Extract.

作者信息

Manh Tran Dinh, Huynh Thanh Liem, Thi Bui Viet, Lee Sunhwa, Yi Junsin, Nguyen Dang Nam

机构信息

Institute of Applied Technology, Thu Dau Mot University, 6 Tran Van on Street, Phu Hoa Ward, Thu Dau Mot City, Binh Duong 820000, Vietnam.

Future Materials & Devices Lab., Institute of Fundamental and Applied Sciences, Duy Tan University, Ho Chi Minh City 700000, Vietnam.

出版信息

ACS Omega. 2022 Mar 1;7(10):8874-8886. doi: 10.1021/acsomega.1c07237. eCollection 2022 Mar 15.

Abstract

leaf extract was characterized for its mitigation of the electrochemical corrosion of steel in naturally aerated hydrochloric acid environments by electrochemical methods and surface analysis. The presence of leaf extract (SCLE) in the hydrochloric acid medium ameliorated the corrosion resistance of steel via the adsorption of SCLE species to form a barrier layer. The improved inhibition effectiveness was demonstrated to be independent of the SCLE concentration and the corrosive environment. The highest inhibition performance of approximately 98% was reached for steel in a 1 M HCl medium containing 2500 ppm SCLE. The performance significantly decreased with a decrease in the HCl concentration from 1.00 to 0.01 M with the same SCLE concentration. In addition, severe corrosion occurred on the uninhibited steel surface but was significantly reduced on the inhibited steel surface. The analyzed results also indicated the existence of electronegative functional groups in SCLE, which could promote the adsorption process for the self-formation of the barrier layer on the steel surface. The work reported herein suggested a powerful strategy to mitigate electrochemical corrosion by adding an effective new inhibitor to achieve a green inhibitor system.

摘要

通过电化学方法和表面分析对叶提取物在自然曝气盐酸环境中减轻钢的电化学腐蚀的性能进行了表征。盐酸介质中叶提取物(SCLE)的存在通过SCLE物种的吸附形成阻挡层,改善了钢的耐腐蚀性。结果表明,提高的缓蚀效果与SCLE浓度和腐蚀环境无关。在含有2500 ppm SCLE的1 M HCl介质中,钢的最高缓蚀性能达到约98%。在相同SCLE浓度下,随着HCl浓度从1.00 M降至0.01 M,性能显著下降。此外,未加缓蚀剂的钢表面发生严重腐蚀,但加了缓蚀剂的钢表面腐蚀明显减轻。分析结果还表明SCLE中存在电负性官能团,这可以促进在钢表面自形成阻挡层的吸附过程。本文报道的工作提出了一种通过添加有效的新型缓蚀剂来减轻电化学腐蚀以实现绿色缓蚀剂体系的有力策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c54a/8928340/e90c4e08a82e/ao1c07237_0002.jpg

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