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In Situ Allene Formation via Alkyne Tautomerization to Promote [4 + 2]-Cycloadditions with a Pendant Alkyne or Nitrile.
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Chemoselective Nitrile Oxide-Alkyne 1,3-Dipolar Cycloaddition Reactions from Nitroalkane-Tethered Peptides.
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Highly regioselective nitrile oxide dipolar cycloadditions with ortho-nitrophenyl alkynes.
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Nickel-Catalyzed Arylative Cyclizations of Alkyne- and Allene-Tethered Electrophiles using Arylboron Reagents.
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Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne.
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Oxidative Dehydrogenation of N-Heteroaromatic Alkyl Alcohols and Amines Facilitated by Dearomative Tautomerization.
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Synthesis and Evaluation of Benzylic F-Labeled -Biphenylalkynyl Nipecotic Acid Derivatives for PET Imaging of GABA Transporter 1.
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1
Synthesis of -Dimethylcyclopentane-Fused Arenes with Various Topologies via TBD-Mediated Dehydro-Diels-Alder Reaction.
J Org Chem. 2021 Dec 3;86(23):16716-16724. doi: 10.1021/acs.joc.1c01957. Epub 2021 Oct 28.
2
The pentadehydro-Diels-Alder reaction.
Nature. 2016 Apr 28;532(7600):484-8. doi: 10.1038/nature17429. Epub 2016 Apr 18.
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Gold(I)-catalyzed diastereoselective hydroacylation of terminal alkynes with glyoxals.
Angew Chem Int Ed Engl. 2014 Jan 20;53(4):1148-51. doi: 10.1002/anie.201307685. Epub 2013 Dec 11.
7
The dehydro-Diels-Alder reaction.
Chem Rev. 2008 Jun;108(6):2051-63. doi: 10.1021/cr0783986. Epub 2008 May 15.
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Intramolecular anionic diels-alder reactions of 1-aryl-4-oxahepta-1,6-diyne systems in DMSO.
J Am Chem Soc. 2007 Apr 25;129(16):4939-47. doi: 10.1021/ja066485u. Epub 2007 Mar 29.

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