氨基硼酸酯的动态共价化学：通过B-N和B-O动态共价键调节rac/rac比例。
The Dynamic Covalent Chemistry of Amidoboronates: Tuning the rac /rac Ratio via the B-N and B-O Dynamic Covalent Bonds.
作者信息
Harders Patrick, Griebenow Thomas, Businski Artjom, Kaus Anton J, Pietsch Lorenz, Näther Christian, McConnell Anna J
机构信息
Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany.
Institute of Inorganic Chemistry, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany.
出版信息
Chempluschem. 2022 May;87(5):e202200085. doi: 10.1002/cplu.202200085. Epub 2022 Mar 22.
Invited for this month's cover is the group of Anna J. McConnell and Christian Näther from Christian-Albrechts-Universität zu Kiel, Germany. The cover picture shows an amidoboronate puzzle divided into four quarters that represent four possible amidoboronates. How do these amidoboronates interconvert? The right combination of aniline (yellow circles) and catechol (grey and purple circles) pieces solves this conundrum and the amidoboronates interconvert via dynamic covalent B-N (left to right) and B-O bonds (top to bottom). More information can be found in the Research Article by Anna J. McConnell and co-workers.
本期封面文章的受邀作者是来自德国基尔基督教-阿尔布雷希特大学的安娜·J·麦康奈尔和克里斯蒂安·内瑟团队。封面图片展示了一个氨基硼酸酯拼图，它被分成四个部分，分别代表四种可能的氨基硼酸酯。这些氨基硼酸酯是如何相互转化的呢？苯胺（黄色圆圈）和儿茶酚（灰色和紫色圆圈）片段的正确组合解决了这个难题，氨基硼酸酯通过动态共价B-N键（从左到右）和B-O键（从上到下）相互转化。更多信息可在安娜·J·麦康奈尔及其同事的研究论文中找到。
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