College of Civil Engineering, Hunan University, Changsha, 410082, Hunan, China.
National Center for International Research Collaboration in Building Safety and Environment, Hunan University, Changsha, 410082, Hunan, China.
Environ Sci Pollut Res Int. 2022 Aug;29(37):55675-55690. doi: 10.1007/s11356-022-19110-4. Epub 2022 Mar 23.
Radiant cooling technology is a sustainable technology for improving built environment. The past research only studied the thermal performance (e.g., radiant heat flux) based on Kirchhoff's law while the accuracy and its reasons were seldom analyzed. This article points out that it is necessary to analyze the precondition before applying Kirchhoff's law directly, because emissivity may not be equal to absorptivity on radiant surfaces. The independence of the emissivity and absorptivity is considered in the new model based on the inapplicability of Kirchhoff's law. The analysis of sensitivity and relative deviation are performed to investigate the reasons for errors. The sensitivity of emissivity is about 20%-40% more sensitive to radiant heat flux than the absorptivity. Furthermore, the deviation of the heat flux can reach up to 20% when the absorptivity is in the range from 0.4 to 0.9. This deviation is close to the error range of 21.8% estimated in the past. Thence, the discussion based on the theoretical analysis, shows that the errors in past studies were highly caused by the oversimplified preconditions for applying Kirchhoff's law and the impact of surface absorption was ignored. Additionally, the validation in the past experiments was highly coincidence, since the key independent tests of the absorptivity and radiant heat flux were neglected. Comprehensively, the new model is valuable to provide a reliable solution for future design and analysis of radiant heat exchange when a radiant surface is not locally equilibrium.
辐射冷却技术是改善建筑环境的可持续技术。过去的研究仅根据基尔霍夫定律研究了热性能(例如,辐射热通量),而很少分析其准确性和原因。本文指出,在直接应用基尔霍夫定律之前,有必要分析其前提条件,因为辐射表面的发射率不一定等于吸收率。在新模型中考虑了发射率和吸收率的独立性,因为基尔霍夫定律不适用。通过分析灵敏度和相对偏差来研究误差的原因。发射率的灵敏度对辐射热通量的灵敏度比吸收率高约 20%-40%。此外,当吸收率在 0.4 到 0.9 之间时,热通量的偏差可达 20%。此偏差接近过去估计的 21.8%的误差范围。因此,基于理论分析的讨论表明,过去研究中的误差主要是由于应用基尔霍夫定律的简化前提条件以及忽略了表面吸收的影响所致。此外,过去的实验验证也高度吻合,因为忽略了吸收率和辐射热通量的关键独立测试。综上所述,对于辐射表面非局部平衡时的辐射热交换的未来设计和分析,新模型为提供可靠的解决方案具有重要价值。