聚[N-(丙烯酰氧基)邻苯二甲酰亚胺]的脱羧反应作为一种通用的聚合后修饰方法。
Decarboxylation of Poly[N-(acryloyloxy)phthalimide] as a Versatile Tool for Postpolymerization Modification.
机构信息
Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76131, Karlsruhe, Germany.
Institute for Biological Interfaces III (IBG-3), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany.
出版信息
Macromol Rapid Commun. 2022 May;43(10):e2200068. doi: 10.1002/marc.202200068. Epub 2022 Apr 7.
Herein the decarboxylation of poly[N-(acryloyloxy)phthalimide] (PAP) for the synthesis of functionalized polymers is reported. PAP homopolymer and block copolymers are used as precursor polymers for the straightforward functionalization via decarboxylation and subsequent Michael-type addition or nitroxide radical coupling (NRC).
本文报道了通过聚N-(丙烯酰氧基)邻苯二甲酰亚胺的脱羧反应合成功能化聚合物。PAP 均聚物和嵌段共聚物可用作前体聚合物，通过脱羧反应以及随后的迈克尔加成或氮氧自由基偶联（NRC）进行简单的功能化。
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