Cl/Br mass ratio and water quality index from the Quaternary aquifer of south Bengal Basin in India.

The purpose of this study is to identify suitable areas for the exploitation of groundwater for human consumption by analysing Cl/Br and other indicators of wastewater influence on groundwater quality in and around the twin megacities of Kolkata and Howrah, located on the complex deltaic system of south Bengal Basin in India. About 18%, 56.5%, 28% and 35.5% of the 287 groundwater samples comply with the Indian acceptable limits (ALs) of TDS, Cl, Fe and Mn, respectively. About 29% of the 279 samples analysed have Cl/Br < 268 where the excess Br is derived from organic degradation. About 30% samples have Cl/Br > 308 clustering mainly around a palaeo-channel indicating wastewater contamination. In addition to these, many samples have NO/Cl > 0.0002 and SO/Cl > 0.014, indicating that the groundwater is contaminated by wastewater from sewage and septic tank leakage. The concentrations of metals (Fe, Mn) and As are also higher than AL particularly on either side of the palaeo-channel, which may affect the human body functions. The localised recharge of wastewater also contains high SO. Sulphate reduction in the aquifer sequesters the As in groundwater into the neo-formed arsenopyrite. Based on the estimated water quality index, the groundwater samples have been classified into four types-highly suitable (28.17%), moderately suitable (23.94%), doubtful (15.85%) and unsuitable (32.04%) for drinking purpose. The first two types cover about 62% of the study area. But the highly urbanised area of Kolkata and Howrah city and the industrial areas in the southern fringe of Kolkata city have the latter two types of groundwater. The over-withdrawal of groundwater may expedite the quality deterioration of 'highly and 'moderately suitable water' of the study area into 'doubtful' and 'unsuitable for drinking' categories through mixing mechanism in the aquifer.