利用纳米纤维素制备含银纳米颗粒的水基导电油墨用于印刷电子学。
Use of Nanocellulose to Produce Water-Based Conductive Inks with Ag NPs for Printed Electronics.
机构信息
Applied Chemistry and Materials, ARTS Department, Leitat Technological Center, C/Pallars, 186-179, 08005 Barcelona, Spain.
Applied Chemistry and Materials, ARTS Department, Leitat Technological Center, C/de la Innovació, 2, 08225 Barcelona, Spain.
出版信息
Int J Mol Sci. 2022 Mar 9;23(6):2946. doi: 10.3390/ijms23062946.
The need for more sustainable printed electronics has emerged in the past years. Due to this, the use of nanocellulose (NC) extracted from cellulose has recently been demonstrated to provide interesting materials such as functional inks and transparent flexible films due to its properties. Its high specific surface area together with the high content of reactive hydroxyl groups provide a highly tailorable surface chemistry with applications in ink formulations as a stabilizing, capping, binding and templating agent. Moreover, NC mechanical, physical and thermal properties (high strength, low porosity and high thermal stability, respectively) provide an excellent alternative for the currently used plastic films. In this work, we present a process for the production of water-based conductive inks that uses NC both as a template for silver nanoparticles (Ag NPs) formation and as an ink additive for ink formulation. The new inks present an electrical conductivity up to 2 × 10 S/m, which is in the range of current commercially available conductive inks. Finally, the new Ag NP/NC-based conductive inks have been tested to fabricate NFC antennas by screen-printing onto NC-coated paper, demonstrating to be operative.
在过去的几年中,人们对更可持续的印刷电子产品的需求日益增长。由于其特性,最近已经证明,从纤维素中提取的纳米纤维素(NC)可用于提供有趣的材料,例如功能性油墨和透明柔性薄膜。其比表面积高,且含有大量反应性羟基,可提供高度可定制的表面化学性质,适用于油墨配方,可用作稳定剂、封端剂、粘合剂和模板剂。此外,NC 的机械、物理和热性能(高强度、低孔隙率和高热稳定性)为目前使用的塑料薄膜提供了极好的替代品。在这项工作中,我们提出了一种使用 NC 作为银纳米颗粒(Ag NPs)形成的模板和作为油墨配方的油墨添加剂来生产水性导电油墨的方法。新型油墨的电导率高达 2×10 S/m,处于当前市售导电油墨的范围内。最后,新型基于 Ag NP/NC 的导电油墨已通过丝网印刷到 NC 涂层纸上进行 NFC 天线的测试,证明是可行的。
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