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用于制造基于纺织品的导电电路和可穿戴式 UHF RFID 标签的 UV 固化导电油墨。

UV Curable Conductive Ink for the Fabrication of Textile-Based Conductive Circuits and Wearable UHF RFID Tags.

出版信息

ACS Appl Mater Interfaces. 2019 Jul 31;11(30):27318-27326. doi: 10.1021/acsami.9b06432. Epub 2019 Jul 22.

Abstract

Textile is a kind of emerging substrate for wearable printed electronics to realize recyclable smart products by versatile and low-cost screen printing. The high temperature sintering step is necessary to get high surface electrical conductivity, whereas most of the common fabrics have poor temperature endurance. Meanwhile, both rough surface and porous structure of fabrics are not beneficial to obtain high-resolution and high-quality circuits. In this work, the ultraviolet (UV) curable conductive inks with low-temperature and short-time curing were developed for screen-printing e-textiles, and the rheological behavior of conductive inks with different polymer contents was characterized in order to determine the ink formulation suitable for screen printing on fabrics. To demonstrate the usability of the developed ink in fabricating e-textiles, the conductive lines with different widths as well as the antenna for UHF RFID tags were screen-printed on plain nylon-woven fabrics. The geometric morphology and the electrical properties of the printed conductive lines were evaluated. The results showed that the screen-printed conductive lines have a minimum line width of 0.2 mm, highest conductivity of 6.02 × 10 S m, and good bending endurance at a bending radius of 5 mm. Also, the feasibility of UV curable conductive ink for a fabric-based electronic device was confirmed by the screen-printed antenna of UHF RFID tags, and the reading distance after five cycles of washing is still over 3.0 m. Generally, this work developed a kind of low-temperature curing ink characterized by direct screen printing on common fabrics and high electrical conductivity after curing, and it will facilitate the use of textiles as the screen-printed substrates for flexible and wearable electronic devices.

摘要

纺织品是可穿戴式印刷电子产品的一种新兴基底材料,通过多功能且低成本的丝网印刷实现可回收的智能产品。为了获得高表面电导率,高温烧结步骤是必要的,而大多数常见的织物的耐温性较差。同时,织物的粗糙表面和多孔结构都不利于获得高分辨率和高质量的电路。在这项工作中,开发了用于丝网印刷电子纺织品的低温和短时间固化的紫外(UV)固化导电油墨,并对具有不同聚合物含量的导电油墨的流变性进行了表征,以确定适合于在织物上丝网印刷的油墨配方。为了展示所开发油墨在制造电子纺织品方面的可用性,在平纹尼龙机织物上丝网印刷了不同宽度的导电线以及用于超高频(UHF)RFID 标签的天线。评估了印刷导电线的几何形态和电性能。结果表明,印刷导电线的最小线宽为 0.2 毫米,最高电导率为 6.02×10 S m,在 5 毫米的弯曲半径下具有良好的弯曲耐久性。此外,通过超高频(UHF)RFID 标签的丝网印刷天线证实了 UV 固化导电油墨用于织物基电子器件的可行性,并且在经过五次洗涤循环后,其读取距离仍超过 3.0 米。总的来说,这项工作开发了一种低温固化油墨,其特点是可以直接在普通织物上进行丝网印刷,并在固化后具有高导电性,这将有助于将纺织品用作柔性和可穿戴电子设备的丝网印刷基底。

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