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硅酸钙矿渣路基材料的试验研究

Experimental Study on Subgrade Material of Calcium Silicate Slag.

作者信息

Zhang De, Yang Zhijie, Kang Dong, Fang Chenyang, Jiao Yang, Mi Shizhong

机构信息

School of Mining and Technology, Inner Mongolia University of Technology, Hohhot 010051, China.

The Key Laboratory of Green Development for Mineral Resources, Inner Mongolia University of Technology, Hohhot 010051, China.

出版信息

Materials (Basel). 2022 Mar 20;15(6):2304. doi: 10.3390/ma15062304.

DOI:10.3390/ma15062304
PMID:35329756
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8955138/
Abstract

Calcium silicate slag (CSS) is used as a secondary solid waste produced by aluminum extraction technology from high alumina fly ash, and its resource utilization has always been a key issue to be solved. In this study, CSS was used to replace a portion of fly ash (FA) to prepare a new inorganic binder stabilized material for road base. The unconfined compressive strength (UCS), phase composition, microstructure, durability and performance index of the base of the test section of the CSS pavement base material were studied. The results showed that with the increase in CSS content, the UCS of pavement base materials gradually increased. Under standard curing conditions, the UCS increased 6.9017.24% after 7 days, and 7.9028.95% after 28 days. The main reason was that as the hydration time increased from 7 d to 28 d, the hydration products C-A-S-H gel and C-S-H gel increased, the [SiO] polymerization degree increased, the crystal type changed, and the structure denser, which supported the good development of mechanical strength of CSS pavement base material. In addition, the research has been successfully applied to a pilot test in Hohhot, China. The freeze-thaw resistance, water stability and UCS of the CSS pavement base material were tested to meet the requirements of Chinese road construction standards, indicating that the application of CSS in pavement base is feasible.

摘要

硅酸钙炉渣(CSS)是高铝粉煤灰提铝工艺产生的一种二次固体废物,其资源利用一直是亟待解决的关键问题。本研究采用CSS替代部分粉煤灰(FA)制备新型无机结合料稳定道路基层材料。对CSS路面基层材料试验段基层的无侧限抗压强度(UCS)、物相组成、微观结构、耐久性及性能指标进行了研究。结果表明,随着CSS含量的增加,路面基层材料的UCS逐渐增大。在标准养护条件下,7d后UCS提高了6.90%17.24%,28d后提高了7.90%28.95%。主要原因是随着水化时间从7d延长至28d,水化产物C-A-S-H凝胶和C-S-H凝胶增多,[SiO]聚合度提高,晶体类型发生变化,结构更加致密,有利于CSS路面基层材料力学强度的良好发展。此外,该研究已在中国呼和浩特成功应用于中试试验。对CSS路面基层材料的抗冻性、水稳定性和UCS进行测试,均满足中国道路建设标准要求,表明CSS在路面基层中的应用是可行的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2263/8955138/1662ac66ef81/materials-15-02304-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2263/8955138/1662ac66ef81/materials-15-02304-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2263/8955138/1662ac66ef81/materials-15-02304-g009.jpg

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本文引用的文献

1
Crystal Evolution of Calcium Silicate Minerals Synthesized by Calcium Silicon Slag and Silica Fume with Increase of Hydrothermal Synthesis Temperature.水热合成温度升高时钙硅渣与硅灰合成硅酸钙矿物的晶体演化
Materials (Basel). 2022 Feb 21;15(4):1620. doi: 10.3390/ma15041620.
2
Utilization of Calcium Carbide Residue as Solid Alkali for Preparing Fly Ash-Based Geopolymers: Dependence of Compressive Strength and Microstructure on Calcium Carbide Residue, Water Content and Curing Temperature.利用电石渣作为固体碱制备粉煤灰基地质聚合物:抗压强度和微观结构对电石渣、含水量及养护温度的依赖性
Materials (Basel). 2022 Jan 27;15(3):973. doi: 10.3390/ma15030973.
3
C-A-S-H Gel and Pore Structure Characteristics of Alkali-Activated Red Mud-Iron Tailings Cementitious Mortar.
碱激发赤泥-铁尾矿胶凝砂浆的孔结构特征及C-A-S-H凝胶
Materials (Basel). 2021 Dec 24;15(1):112. doi: 10.3390/ma15010112.
4
Comparison between CaO- and MgO-activated ground granulated blast-furnace slag (GGBS) for stabilization/solidification of Zn-contaminated clay slurry.比较 CaO 和 MgO 激活的粒化高炉矿渣(GGBS)对 Zn 污染的粘土泥浆的稳定/固化作用。
Chemosphere. 2022 Jan;286(Pt 3):131860. doi: 10.1016/j.chemosphere.2021.131860. Epub 2021 Aug 10.
5
Calcium hydroxide content and hydration degree of cement in cementitious composites containing calcium silicate slag.含钙硅酸渣水泥基复合材料中氢氧化钙含量和水泥水合程度。
Chemosphere. 2021 Oct;280:130918. doi: 10.1016/j.chemosphere.2021.130918. Epub 2021 May 17.
6
Effects of Calcium Silicate Slag on Hydration of Cementitious Pastes.硅酸钙矿渣对水泥净浆水化的影响。
Materials (Basel). 2019 Sep 23;12(19):3094. doi: 10.3390/ma12193094.
7
High calcium fly ash geopolymer stabilized lateritic soil and granulated blast furnace slag blends as a pavement base material.高钙粉煤灰地质聚合物稳定红土和矿渣混合物作为路面基层材料。
J Hazard Mater. 2018 Jan 5;341:257-267. doi: 10.1016/j.jhazmat.2017.07.067. Epub 2017 Jul 31.