五至七元环α-重氮单羰基化合物的制备及合成应用。
Preparation and Synthetic Applications of Five-to-Seven-Membered Cyclic α-Diazo Monocarbonyl Compounds.
机构信息
Research & Development Department, BratskChemSyntez LLC, PharmaSyntez Company, 5A/1 Kommunalnaya St., 665717 Bratsk, Russia.
Institute of Chemistry, Saint Petersburg State University, 199034 Saint Petersburg, Russia.
出版信息
Molecules. 2022 Mar 21;27(6):2030. doi: 10.3390/molecules27062030.
Abstract
The reactivity of cyclic α-diazo monocarbonyl compounds differs from that of their acyclic counterparts. In this review, we summarize the current literature available on the synthesis and synthetic applications of three major classes of cyclic α-diazo monocarbonyl compounds: α-diazo ketones, α-diazo lactones and α-diazo lactams.
摘要
环状α-重氮单羰基化合物的反应活性与无环类似物不同。在这篇综述中，我们总结了目前关于三类主要环状α-重氮单羰基化合物（α-重氮酮、α-重氮内酯和α-重氮内酰胺）的合成和合成应用的文献。
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