Fabrication of TiO/NiO p-n Nanocomposite for Enhancement Dye Photodegradation under Solar Radiation.

A p-n nanocomposite based on TiO nanotubes (NTs) and NiO nanoparticles (NPs) was designed and optimized in this study to improve the photocatalytic performance of methylene blue (MB). The hydrothermal technique has been used to produce TiO/NiO nanocomposites with different NiO NPs weight ratios; 1TiO:1NiO, 1TiO:2NiO, and 1TiO:3NiO. The crystal phase, chemical composition, optical properties, and morphology of TiO/NiO were explored by various techniques. TiO NTs have a monoclinic structure, while NiO NPs have a cubic structure, according to the structural study. The bandgap of TiO NTs was reduced from 3.54 eV to 2.69 eV after controlling the NiO NPs weight ratio. The TiO/2NiO nanocomposite showed the best photodegradation efficiency. Within 45 min of solar light irradiation, the efficiency of MB dye degradation using TiO/2NiO hits 99.5% versus 73% using pure TiO NTs. Furthermore, the catalytic photodegradation efficiency did not deteriorate significantly even after five reusability cycles, intimating the high stability of the TiO/2NiO nanocomposite. This suggests that the loading of NiO NPs into TiO NTs lowers the recombination of photo-produced electron/hole pairs and enlarged solar spectral response range, which results in improved photocatalytic activity. The mechanism of charge transfer in the TiO/NiO and kinetic models were discussed for the photodegradation of MB.