Zhou Zheng, Zhu Yikun, Fernández-García Jesús M, Wei Zheng, Fernández Israel, Petrukhina Marina A, Martín Nazario
Department of Chemistry, University at Albany, State University of New York Albany, NY 12222, USA.
School of Materials Science and Engineering, Tongji University, 4800 Cao'an Road, Shanghai 201804, China.
Chem Commun (Camb). 2022 May 5;58(37):5574-5577. doi: 10.1039/d2cc00971d.
The chemical reduction of a corannulene-based molecular nanographene, CH (1), with Na metal in the presence of 18-crown-6 afforded the doubly-reduced state of 1. This reduction provokes a distortion of the helicene core and has a significant impact on the aromaticity of the system.
在18-冠-6存在的情况下，用金属钠对基于碗烯的分子纳米石墨烯CH(1)进行化学还原，得到了1的双还原态。这种还原引发了螺旋烯核心的扭曲，并对该体系的芳香性产生了重大影响。
