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一种调节碳化聚合物点光致发光的创新方法。

An innovative way to modulate the photoluminescence of carbonized polymer dots.

作者信息

Li Pengfei, Sun Zaicheng

机构信息

Center of Excellence for Environmental Safety and Biological Effects, Beijing Key Laboratory for Green Catalysis and Separation, Faculty of Environment and Life, Beijing University of Technology, Beijing, 100124, P. R. China.

出版信息

Light Sci Appl. 2022 Mar 30;11(1):81. doi: 10.1038/s41377-022-00772-1.

DOI:10.1038/s41377-022-00772-1
PMID:35354785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8967849/
Abstract

Cross-linking enhances the photoluminescence quantum yield of carbonized polymer dots, in which confined-domain promotes the energy level overlap, redshifts emission wavelength, and facilitates phosphorescence generation.

摘要

交联提高了碳化聚合物点的光致发光量子产率,其中受限域促进了能级重叠,使发射波长红移,并促进了磷光的产生。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f9d/8967849/6c23930c9b38/41377_2022_772_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f9d/8967849/b215051e0a8c/41377_2022_772_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f9d/8967849/6c23930c9b38/41377_2022_772_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f9d/8967849/b215051e0a8c/41377_2022_772_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1f9d/8967849/6c23930c9b38/41377_2022_772_Fig2_HTML.jpg

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本文引用的文献

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Confined-domain crosslink-enhanced emission effect in carbonized polymer dots.碳化聚合物点中的受限域交联增强发射效应
Light Sci Appl. 2022 Mar 10;11(1):56. doi: 10.1038/s41377-022-00745-4.
2
Multicolor polymeric carbon dots: synthesis, separation and polyamide-supported molecular fluorescence.多色聚合物碳点:合成、分离及聚酰胺负载分子荧光
Chem Sci. 2020 Dec 22;12(7):2441-2455. doi: 10.1039/d0sc05743f.
3
Lifetime-Engineered Carbon Nanodots for Time Division Duplexing.用于时分双工的寿命工程化碳纳米点
Adv Sci (Weinh). 2021 Feb 1;8(6):2003433. doi: 10.1002/advs.202003433. eCollection 2021 Mar.
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Unraveling the Fluorescence Mechanism of Carbon Dots with -Single-Particle Resolution.以单颗粒分辨率解析碳点的荧光机制
ACS Nano. 2020 May 26;14(5):6127-6137. doi: 10.1021/acsnano.0c01924. Epub 2020 Apr 28.
5
Surface related intrinsic luminescence from carbon nanodots: solvent dependent piezochromism.碳点的表面相关本征发光:溶剂依赖的压致变色。
Nanoscale Horiz. 2019 Jan 1;4(1):175-181. doi: 10.1039/c8nh00258d. Epub 2018 Oct 2.
6
Crosslink-Enhanced Emission Effect on Luminescence in Polymers: Advances and Perspectives.聚合物中交联增强发射对发光的影响:进展与展望
Angew Chem Int Ed Engl. 2020 Jun 15;59(25):9826-9840. doi: 10.1002/anie.201916591. Epub 2020 Apr 1.
7
sp-sp-Hybridized Atomic Domains Determine Optical Features of Carbon Dots.sp-sp 杂化原子域决定碳点的光学特性。
ACS Nano. 2019 Sep 24;13(9):10737-10744. doi: 10.1021/acsnano.9b05444. Epub 2019 Aug 19.
8
Hydrophobic carbon dots with blue dispersed emission and red aggregation-induced emission.具有蓝色分散发射和红色聚集诱导发射的疏水碳点。
Nat Commun. 2019 Apr 17;10(1):1789. doi: 10.1038/s41467-019-09830-6.
9
White light emission from a single organic molecule with dual phosphorescence at room temperature.室温下单分子的双磷光发白光。
Nat Commun. 2017 Sep 4;8(1):416. doi: 10.1038/s41467-017-00362-5.
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Adv Mater. 2017 Oct;29(37). doi: 10.1002/adma.201702910. Epub 2017 Jul 31.