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由结晶前体制备的无定形金属有机骨架,用于高容量碘捕获。

Amorphous metal-organic frameworks obtained from a crystalline precursor for the capture of iodine with high capacities.

机构信息

School of Chemistry, Guangzhou Key Laboratory of Analytical Chemistry for Biomedicine, South China Normal University, Guangzhou, 510006, China. zhengsr-scnu.edu.cn.

School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China.

出版信息

Chem Commun (Camb). 2022 Apr 19;58(32):5013-5016. doi: 10.1039/d1cc07229c.

Abstract

Two amorphous metal-organic frameworks (MOFs) were obtained from crystalline Co-MOF (SCNU-Z6) temperature-induced (-SCNU-Z6) and water-immersed (-SCNU-Z6) approaches. They exhibited high iodine uptake, with the adsorption capacities of -SCNU-Z6 and -SCNU-Z6 reaching 2.05 and 5.04 g g, respectively. This work is the first report of iodine uptake by MOFs.

摘要

两种无定形金属-有机骨架(MOFs)通过结晶 Co-MOF(SCNU-Z6)的温度诱导(-SCNU-Z6)和水浸泡(-SCNU-Z6)方法获得。它们表现出高碘摄取能力,-SCNU-Z6 和 -SCNU-Z6 的吸附容量分别达到 2.05 和 5.04 g g。这项工作是 MOFs 吸附碘的首次报道。

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