Opt Lett. 2022 Apr 1;47(7):1907-1910. doi: 10.1364/OL.448177.
Circular dichroism (CD) is required in the applications of biological detection, analytical chemistry, etc. Here, we numerically demonstrated large-range switchable CD by controlling the phase change of GeSbTe (GST) in a zigzag array. At the amorphous state of GST (a-GST), the strong and dual-waveband CD effects are realized via the selective excitations of electric, magnetic, and toroidal resonances. With the transition from a-GST to crystalline state GST, CD strengths are tailored dynamically in large ranges. In detail, the CD magnitudes change by about 0.93 and the modulation depths exceed 94% at dual wavebands. The strong CD effects and large-range switch capability in the GST-based metasurfaces will boost the development of active chiroptical devices.
圆二色性(CD)在生物检测、分析化学等应用中是必需的。在这里,我们通过控制锯齿形排列的锗锑碲(GST)的相变化,数值证明了大范围可切换的 CD。在 GST 的非晶态(a-GST)下,通过对电、磁和环形共振的选择性激发,实现了强双波段 CD 效应。随着 GST 从非晶态向晶态转变,CD 强度可以在很大范围内动态调整。具体来说,在双波段下,CD 幅度变化约为 0.93,调制深度超过 94%。基于 GST 的超表面具有较强的 CD 效应和大范围切换能力,将推动主动手性器件的发展。