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聚[[双-(水合-κ)四-双-(μ-4,4'-联吡啶-κ:')六-双-(3-氯苯甲酸根)-κ;κ:'-三钴(II)]]甲醇溶剂合物的合成与晶体结构

Synthesis and crystal structure of poly[[bis-(aqua-κ)tetra-kis-(μ-4,4'-bi-pyridine-κ :')hexa-kis-(3-chloro-benzoato)-κ ;κ :'-tricobalt(II)] methanol disolvate].

作者信息

Promwit Phakamat, Chainok Kittipong, Wannarit Nanthawat

机构信息

Department of Chemistry, Faculty of Science and Technology, Thammasat University, Klong Luang, Pathum Thani 12121, Thailand.

Thammasat University Research Unit in Multifunctional Crystalline Materials and Applications (TU-MCMA), Faculty of Science and Technology, Thammasat University, Klong Luang, Pathum Thani 12121, Thailand.

出版信息

Acta Crystallogr E Crystallogr Commun. 2022 Feb 1;78(Pt 3):255-258. doi: 10.1107/S2056989022000731.

DOI:10.1107/S2056989022000731
PMID:35371544
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8900501/
Abstract

A novel ladder-chain cobalt(II) coordination polymer, {[Co(CHClO)(CHN)(HO)]·2CHOH} , was synthesized and characterized. The structure contains two Co centres with different octa-hedral environments, [Co(1)NO] and [Co(2)NO]. The -donating 3-chloro-benzoate anions (3-Clbenz) act as the terminal ligands, while the -donating 4,4'-bipy mol-ecules play the role of linkers. The Co(1) ions are linked by 4,4'-bipy mol-ecules into linear chains. Two such chains are joined by [Co(2)(3-Clbenz)(HO)] units two 4,4'-bipy bridging ligands, thus forming the ladder-chain structure. The crystal packing of the title compound is stabilized by supra-molecular inter-actions, such as hydrogen bonding, π-π and halogen⋯π contacts, giving a three-dimensional framework. The spectroscopic and thermal properties of the title compound have also been investigated.

摘要

合成并表征了一种新型的梯链钴（II）配位聚合物{[Co(CHClO)(CHN)(HO)]·2CHOH} 。该结构包含两个具有不同八面体环境的钴中心，即[Co(1)NO]和[Co(2)NO]。具有给电子能力的3-氯苯甲酸根阴离子（3-Clbenz）作为末端配体，而具有给电子能力的4,4'-联吡啶分子则充当连接体。Co(1)离子通过4,4'-联吡啶分子连接成线性链。两条这样的链通过[Co(2)(3-Clbenz)(HO)]单元和两个4,4'-联吡啶桥连配体相连，从而形成梯链结构。标题化合物的晶体堆积通过诸如氢键、π-π和卤素⋯π接触等超分子相互作用得以稳定，形成三维框架。还研究了标题化合物的光谱和热性质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/c1e53fae8c67/e-78-00255-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/c230648bf0b1/e-78-00255-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/ea1aad098590/e-78-00255-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/ffc683748930/e-78-00255-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/c1e53fae8c67/e-78-00255-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/c230648bf0b1/e-78-00255-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/ea1aad098590/e-78-00255-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/ffc683748930/e-78-00255-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6ae/8900501/c1e53fae8c67/e-78-00255-fig4.jpg

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Synthesis and crystal structure of poly[[bis-(aqua-κ)tetra-kis-(μ-4,4'-bi-pyridine-κ :')hexa-kis-(3-chloro-benzoato)-κ ;κ :'-tricobalt(II)] methanol disolvate].聚[[双-(水合-κ)四-双-(μ-4,4'-联吡啶-κ:')六-双-(3-氯苯甲酸根)-κ;κ:'-三钴(II)]]甲醇溶剂合物的合成与晶体结构
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