Kalinke Lucas H G, Rabelo Renato, Valdo Ana K, Martins Felipe T, Moliner Nicolás, Ferrando-Soria Jesus, Julve Miguel, Lloret Francesc, Cano Joan, Cangussu Danielle
Instituto Federal de Goiás, IFG-Câmpus Anápolis, Anápolis, Goiás 75131-457, Brazil.
Departament de Química Inorgànica, Instituto de Ciencia Molecular, 46980 C/Catedrático José Beltrán 2, Paterna, Valencia 46980, Spain.
Inorg Chem. 2022 Apr 18;61(15):5696-5700. doi: 10.1021/acs.inorgchem.2c00291. Epub 2022 Apr 6.
The cobalt(II)-mediated self-assembly of the potentially tris(chelating) ,'-2,2'-(4,4'-bithiazole)bis(oxamate) (dabtzox) ligand gives a new metal-organic supramolecular nanomagnet of formula KCo(dabtzox)·8HO·MeOH () featuring a unique linear triple-stranded trinuclear structure of the helicate type.
钴(II)介导的潜在三(螯合)的'-2,2'-(4,4'-联噻唑)双(草氨酸)(dabtzox)配体的自组装产生了一种新的金属有机超分子纳米磁体,其化学式为KCo(dabtzox)·8H₂O·MeOH(),具有独特的螺旋型线性三链三核结构。