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[重庆工业源挥发性有机物物种排放清单及其臭氧生成潜势]

[Speciated Emission Inventory of VOCs from Industrial Sources and Their Ozone Formation Potential in Chongqing].

作者信息

Li Ling, Li Zhen-Liang, Fang Wei-Kai, Wang Xiao-Chen, Pu Xi, Wang Ling-Tao, Yuan Rui, Zhang Wei-Dong, Zhai Chong-Zhi

机构信息

Key Laboratory for Urban Atmospheric Environment Integrated Observation & Pollution Prevention and Control of Chongqing, Chongqing Research Academy of Eco-Environmental Sciences, Chongqing 401147, China.

出版信息

Huan Jing Ke Xue. 2022 Apr 8;43(4):1756-1765. doi: 10.13227/j.hjkx.202108015.

Abstract

Based on the basic information of the Second National Pollution Source Census and the VOCs source profiles of industrial industries, we established the speciated emission inventory of major industrial sources in Chongqing in 2017, estimated their ozone formation potential (OFP), and identified the key control species of industrial VOCs and their sources. The results showed that the total VOCs emission from industrial sources and their OFPs were 144.12 kt and 477.34 kt, respectively. Automobile manufacturing, equipment manufacturing, plastic manufacturing, and chemical raw materials and chemical products were all industries that contributed significantly to VOCs emissions and OFP, with VOCs emissions of 37.18, 33.09, 19.47, and 18.14 kt and OFP of 191.43, 153.69, 27.21, and 57.51 kt, respectively. Aromatics were the components with the largest contribution to VOCs emissions and OFP, accounting for 62.55% of the total VOCs emissions and 82.15% of the total OFP, mainly from metal surface coating and petrochemical industries. The major reactive species of industrial source VOCs were -xylene, toluene, ethylbenzene, -xylene, and propylene, with OFP of 130.47, 103.37, 46.37, 42.83, and 28.26 kt, respectively, cumulatively accounting for 71.11% of the total OFP. In terms of spatial distribution, the emission intensity of VOCs and O pollution degree in all districts and counties of Chongqing were relatively consistent; the high value points of VOCs emissions and OFP were mainly distributed in the main urban area and the western area, and the sources of VOCs emission in the main urban area and western area were mainly in metal surface coating and the petrochemical industry, respectively.

摘要

基于第二次全国污染源普查的基础信息和工业行业挥发性有机物(VOCs)源谱,我们建立了2017年重庆市主要工业源的物种排放清单,估算了其臭氧生成潜势(OFP),并确定了工业VOCs的关键控制物种及其来源。结果表明,工业源VOCs总排放量及其OFP分别为144.12 kt和477.34 kt。汽车制造、装备制造、塑料制品制造以及化学原料和化学制品制造均是对VOCs排放和OFP贡献显著的行业,其VOCs排放量分别为37.18 kt、33.09 kt、19.47 kt和18.14 kt,OFP分别为191.43 kt、153.69 kt、27.21 kt和57.51 kt。芳烃是对VOCs排放和OFP贡献最大的组分,占VOCs排放总量的62.55%,占OFP总量的82.15%,主要来自金属表面涂装和石化行业。工业源VOCs的主要活性物种为间二甲苯、甲苯、乙苯、邻二甲苯和丙烯,其OFP分别为130.47 kt、103.37 kt、46.37 kt、42.83 kt和28.26 kt,累计占OFP总量的71.11%。在空间分布方面,重庆市各区县VOCs排放强度与O污染程度较为一致;VOCs排放和OFP的高值点主要分布在主城区和西部地区,主城区和西部地区VOCs排放源分别主要集中在金属表面涂装和石化行业。

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