Fabrication of a Covalent Organic Framework-Based Heterojunction via Coupling with ZnAgInS Nanosphere with High Photocatalytic Activity.

Covalent organic frameworks (COFs) exhibit visible-light activity for the degradation of organic pollutants. However, the recombination rates of their photoinduced electron-hole pairs are relatively high, limiting their practical application. In this work, we fabricated a 1,3,5-triformylphloroglucinol (Tp) and -phenylenediamine (Pa-1) (TpPa-1) COF-based heterojunction through coupling the TpPa-1 COF with a ZnAgInS nanosphere via a facile oil bath heating method. The results show that the prepared heterojunction exhibits outstanding catalytic activity for the degradation of high concentrations the antibiotic tetracycline (TC) and the dye rhodamine B (RhB), which is driven by simulated sunlight. Its degradation rates for RhB and TC were 30× and 18× higher than that of the pure TpPa-1 COF, respectively. The greatly enhanced photocatalytic performances can be ascribed to the formed heterojunction with good band-gap match, which promotes the migration and separation of light-induced electrons and holes and increases both light absorbance and the specific surface area. This study introduces an effective and feasible strategy for improving the photocatalytic performances of COFs via subtly integrating TpPa-1 COFs with a ZnAgInS nanosphere into an organic-inorganic hybrid. The results of the photocatalytic experiments indicate that the fabricated hybrid has a potential application in the highly efficient removal of organic pollutants.