Shen Junshi, Hu Ruofei, Jiang Xueliang, You Feng, Yao Chu, Yang Huan, Yu Peng
Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, China.
Department of Food Science & Chemical Engineering, Hubei University of Arts and Science, Xiangyang 441053, China.
Polymers (Basel). 2022 Mar 26;14(7):1344. doi: 10.3390/polym14071344.
In this study, Arabic gum/ carboxylic butadiene-acrylonitrite latex aerogels (AG/XNBRL) hybrid aerogel was successfully prepared by a green method, i.e., the combination of latex compounding and vacuum freeze-drying process. After that, the obtained composites were subjected to a high temperature treatment to crosslink the rubber phase. It was found that the AG in the AG/XNBRL hybrid aerogel could act as a framework to improve the dimensional stability of the aerogel, while the XNBRL phase could significantly improve the mechanical flexibility of the ensuing composite. Compared to the AG aerogel which is highly brittle in nature, the AG/XNBRL hybrid aerogel not only exhibits significantly enhanced toughness, but also shows improved thermal stability and sound absorption performances; for instance, the half weight loss (50%) temperature and average sound adsorption coefficient for aerogel containing 30 wt% XNBRL is 344 °C and 0.585, respectively, which are superior to those of neat AG aerogel. Overall, this work provides novel inspiration to prepare the mechanical robust bio-based aerogel for the sound absorption application.
在本研究中,通过绿色方法,即胶乳复合与真空冷冻干燥工艺相结合,成功制备了阿拉伯胶/羧基丁二烯 - 丙烯腈胶乳气凝胶(AG/XNBRL)杂化气凝胶。之后,对所得复合材料进行高温处理以使橡胶相交联。结果发现,AG/XNBRL杂化气凝胶中的AG可作为一种骨架来提高气凝胶的尺寸稳定性,而XNBRL相可显著提高后续复合材料的机械柔韧性。与本质上高度脆性的AG气凝胶相比,AG/XNBRL杂化气凝胶不仅韧性显著增强,而且热稳定性和吸声性能也有所改善;例如,含30 wt% XNBRL的气凝胶的半失重(50%)温度和平均吸声系数分别为344℃和0.585,优于纯AG气凝胶。总体而言,这项工作为制备用于吸声应用的机械坚固的生物基气凝胶提供了新的灵感。