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基于絮体结构特征微观表征的分级细尾矿絮凝剂选型研究

Research on Flocculant Selection for Classified Fine Tailings Based on Micro-Characterization of Floc Structure Characteristics.

作者信息

Tan Yuye, Meng Xiang, Jiang Zhiwei, Han Chongchong, Guo Mochuan

机构信息

Key Laboratory of the Ministry of Education for High Efficient Mining and Safety in Mental Mines, Beijing 100083, China.

School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China.

出版信息

Materials (Basel). 2022 Mar 27;15(7):2460. doi: 10.3390/ma15072460.

Abstract

The rapid settlement of tailings is an important technical guarantee for the continuous production of downhole filling. The selection of a reasonable flocculant is essential for accelerating the settlement speed of classified fine tailings. The present paper conducts indoor static sedimentation experiments, NMR observation, electron microscope scanning, and other methods to analyze the porosity and pore-size distribution characteristics of floc solution for classified fine tailing under four flocculants, namely, ZYZ, ZYD, JYC-1, and JYC-2. The dimension, spatial distribution characteristics, particle size characteristics, and morphological characteristics of the scanning electron microscope images of floc were studied. Results show that the unit consumption of flocculant at 30 g/t is the critical value for increasing the flocculation and sedimentation effect of the classified fine tailings solution. The highest distribution percentage of small-sized classified fine tailings and the lowest average pore size was observed under the ZYZ-type flocculant. This flocculant also obtained the lowest porosity, largest average floc size, largest area occupied by the floc, lowest pore percentage, and the densest floc structure. Thus, this flocculant showed the best flocculation effect. A negative correlation was observed between the equivalent diameter of floc with varying settlement heights. The dimension of floc increased with the decrease in bed settlement height, and the overall structure of the floc gradually transitioned from loose to dense from top to bottom. The present paper characterizes the microscopic morphology and spatial structure characteristics of floc under different flocculants from a microscopic point of view. The present paper also provides a scientific basis for the selection of the optimal flocculant.

摘要

尾矿的快速沉降是井下充填连续生产的重要技术保障。选择合理的絮凝剂对于加快分级细尾矿的沉降速度至关重要。本文通过室内静态沉降实验、核磁共振观测、电子显微镜扫描等方法,分析了ZYZ、ZYD、JYC - 1和JYC - 2这四种絮凝剂作用下分级细尾矿絮凝体溶液的孔隙率和孔径分布特征。研究了絮凝体扫描电子显微镜图像的尺寸、空间分布特征、粒度特征和形态特征。结果表明,絮凝剂用量30 g/t是提高分级细尾矿溶液絮凝沉降效果的临界值。在ZYZ型絮凝剂作用下,小粒径分级细尾矿的分布百分比最高,平均孔径最小。该絮凝剂还具有最低的孔隙率、最大的平均絮凝体尺寸、絮凝体占据的最大面积、最低的孔隙百分比和最致密的絮凝结构。因此,该絮凝剂表现出最佳的絮凝效果。不同沉降高度下絮凝体的等效直径呈负相关。絮凝体尺寸随床层沉降高度的降低而增大,絮凝体总体结构由上至下逐渐由松散过渡到致密。本文从微观角度表征了不同絮凝剂作用下絮凝体的微观形态和空间结构特征,为优选最佳絮凝剂提供了科学依据。

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