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温度和外加电位对X80钢在忻州模拟土壤溶液中应力腐蚀开裂的影响

Effects of Temperature and Applied Potential on the Stress Corrosion Cracking of X80 Steel in a Xinzhou Simulated Soil Solution.

作者信息

Cheng Yuan, Liu Peng, Yang Mengmeng

机构信息

National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China.

出版信息

Materials (Basel). 2022 Mar 31;15(7):2560. doi: 10.3390/ma15072560.

Abstract

In this research, the stress corrosion cracking (SCC) behavior of X80 pipeline steel in a Xinzhou soil environment at different temperatures and applied potentials was studied with a slow strain rate test (SSRT), potentiodynamic polarization curve measurements, and scanning electron microscopy (SEM). When a higher anodic potential was applied, anodic dissolution occurred at the crack tip and on the crack wall. The cracking mechanism of X80 steel in Xinzhou soil solution is anodic dissolution (AD). At positive cathodic potentials, X80 steel is under an anodic polarization state at the crack tip and under a cathodic polarization state at the crack wall. The SCC of X80 steel is affected by the combined effects of anodic dissolution (AD) and hydrogen embrittlement (HE). At more negative cathodic potentials, both crack tips and crack walls are under cathodic polarization. The SCC of X80 steel is dominated by hydrogen embrittlement (HE). SCC susceptibility has the same variation trend with potentials at different temperatures. The susceptibility to SCC increases notably as the temperature increases at weak cathodic potentials and open circuit potential due to the effect of temperature on the corrosion potential and the diffusion of atoms.

摘要

本研究采用慢应变速率试验(SSRT)、动电位极化曲线测量和扫描电子显微镜(SEM),研究了X80管线钢在忻州土壤环境中不同温度和外加电位下的应力腐蚀开裂(SCC)行为。当施加较高的阳极电位时,裂纹尖端和裂纹壁上发生阳极溶解。X80钢在忻州土壤溶液中的开裂机制为阳极溶解(AD)。在正的阴极电位下,X80钢在裂纹尖端处于阳极极化状态,在裂纹壁处于阴极极化状态。X80钢的应力腐蚀开裂受阳极溶解(AD)和氢脆(HE)的共同作用影响。在更负的阴极电位下,裂纹尖端和裂纹壁均处于阴极极化状态。X80钢的应力腐蚀开裂以氢脆(HE)为主导。在不同温度下,应力腐蚀开裂敏感性随电位具有相同的变化趋势。由于温度对腐蚀电位和原子扩散的影响,在弱阴极电位和开路电位下,随着温度升高,应力腐蚀开裂敏感性显著增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e74/9000137/1be90243adbd/materials-15-02560-g001.jpg

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