• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

LuAG:Ce薄膜的超声喷雾热解合成及光致发光

Ultrasonic Spray Pyrolysis Synthesis and Photoluminescence of LuAG:Ce Thin Films.

作者信息

Wang Tingting, Xue Bingguo, Cui Hao, Zhang Yingying, Liu Manmen, Chen Jialin, Wen Ming, Wang Wei, Sun Xudong, Liu Shaohong

机构信息

Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China.

State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China.

出版信息

Materials (Basel). 2022 Mar 31;15(7):2577. doi: 10.3390/ma15072577.

DOI:10.3390/ma15072577
PMID:35407909
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8999763/
Abstract

LuAG:Ce (LuAlO:Ce) is one of the most important color converters in white lighting industry. Especially, LuAG:Ce film attracts more attention due to the outstanding advantages, such as the efficient heat dissipation, the saving of rare earth, and so on. Here, LuAG:Ce film on sapphire was successfully prepared by the ultrasonic spray pyrolysis process. The phase, microstructure and photoluminescence of LuAG:Ce films were investigated. LuAG:Ce films had a thickness of around 5 μm, which were well crystallized at 1000 °C in air atmosphere to form the typical garnet structure. Under the protection of CO atmosphere, increasing the annealing temperature greatly enhanced the photoluminescence performance. After annealing at 1500 °C for 5 h in CO atmosphere, 3.0 mol.% Ce doped LuAG:Ce film exhibited the highest emission and excitation intensity. The emission intensity of 3.0 mol.% Ce doped LuAG:Ce film annealed at 1500 °C in CO atmosphere increased up to five times, when compared with the best LuAG:Ce film annealed at 1000 °C in air atmosphere. The effects of Ce doping concentration on the photoluminescence were also examined. As the Ce doping concentration increased from 0.2 mol.% to 7.0 mol.%, the color of LuAG:Ce films changed from yellowish green to greenish yellow. When coupling the 3.0 mol.% Ce doped LuAG:Ce film with a 0.5 W 450 nm blue laser, the formed device successfully emitted white light.

摘要

LuAG:Ce（LuAlO:Ce）是白色照明行业中最重要的颜色转换材料之一。特别是，LuAG:Ce薄膜因其高效散热、节省稀土等突出优点而备受关注。在此，通过超声喷雾热解工艺成功制备了蓝宝石上的LuAG:Ce薄膜。对LuAG:Ce薄膜的相、微观结构和光致发光进行了研究。LuAG:Ce薄膜厚度约为5μm，在空气气氛中1000℃下良好结晶，形成典型的石榴石结构。在CO气氛保护下，提高退火温度可大大增强光致发光性能。在CO气氛中1500℃退火5h后，3.0mol.%Ce掺杂的LuAG:Ce薄膜表现出最高的发射和激发强度。与在空气气氛中1000℃退火的最佳LuAG:Ce薄膜相比，在CO气氛中1500℃退火的3.0mol.%Ce掺杂的LuAG:Ce薄膜的发射强度提高了五倍。还研究了Ce掺杂浓度对光致发光的影响。随着Ce掺杂浓度从0.2mol.%增加到7.0mol.%，LuAG:Ce薄膜的颜色从黄绿色变为绿黄色。当将3.0mol.%Ce掺杂的LuAG:Ce薄膜与0.5W 450nm蓝色激光耦合时，所形成的器件成功发射出白光。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/9490b19a9a6d/materials-15-02577-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/ff424174decc/materials-15-02577-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/711a8c1471d7/materials-15-02577-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/a4b79eb9ceed/materials-15-02577-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/a7702910ea36/materials-15-02577-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/1f826dca71ae/materials-15-02577-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/4d83c05aee50/materials-15-02577-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/c8feeb32da10/materials-15-02577-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/9490b19a9a6d/materials-15-02577-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/ff424174decc/materials-15-02577-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/711a8c1471d7/materials-15-02577-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/a4b79eb9ceed/materials-15-02577-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/a7702910ea36/materials-15-02577-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/1f826dca71ae/materials-15-02577-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/4d83c05aee50/materials-15-02577-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/c8feeb32da10/materials-15-02577-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd28/8999763/9490b19a9a6d/materials-15-02577-g008.jpg

相似文献

1
Ultrasonic Spray Pyrolysis Synthesis and Photoluminescence of LuAG:Ce Thin Films.LuAG:Ce薄膜的超声喷雾热解合成及光致发光
Materials (Basel). 2022 Mar 31;15(7):2577. doi: 10.3390/ma15072577.
2
High luminous efficiency and high saturation threshold in highly transparent LuAG:Ce phosphor ceramics for laser diodes lighting.用于激光二极管照明的高透明LuAG:Ce荧光粉陶瓷中的高发光效率和高饱和阈值。
Opt Express. 2024 Jan 15;32(2):2644-2657. doi: 10.1364/OE.510121.
3
Development of Three-Layered Composite Color Converters for White LEDs Based on the Epitaxial Structures of YAG:Ce, TbAG:Ce and LuAG:Ce Garnets.基于YAG:Ce、TbAG:Ce和LuAG:Ce石榴石外延结构的白光发光二极管三层复合颜色转换器的研制
Materials (Basel). 2023 Feb 23;16(5):1848. doi: 10.3390/ma16051848.
4
Highly efficient Ce: Lu(Mg,Al)(Si,Al)O phosphor ceramics for high-power white LEDs/LDs.用于高功率白光发光二极管/激光二极管的高效铈掺杂钇铝石榴石荧光陶瓷
Opt Express. 2022 Jul 4;30(14):25078-25092. doi: 10.1364/OE.463022.
5
Three-Layered Composite Scintillator Based on the Epitaxial Structures of YAG and LuAG Garnets Doped with Ce and Sc Impurities.基于掺杂Ce和Sc杂质的YAG和LuAG石榴石外延结构的三层复合闪烁体。
Materials (Basel). 2024 Aug 13;17(16):4025. doi: 10.3390/ma17164025.
6
Ce, Pr Co-Doped LuAlO Single Crystals and Ceramics: A Comparative Study.铈、镨共掺杂的钇铝石榴石单晶与陶瓷：一项对比研究。
Materials (Basel). 2022 Dec 17;15(24):9025. doi: 10.3390/ma15249025.
7
Hybrid 2D photonic crystal-assisted Lu3Al5O12:Ce ceramic-plate phosphor and free-standing red film phosphor for white LEDs with high color-rendering index.Hybrid 2D 光子晶体辅助 Lu3Al5O12:Ce 陶瓷板磷光体和独立式红色薄膜磷光体，用于具有高显色指数的白光 LEDs。
ACS Appl Mater Interfaces. 2015 Mar 4;7(8):4549-59. doi: 10.1021/am507237n. Epub 2015 Feb 23.
8
[Effects of different annealing conditions on the photoluminescence of nanoporous alumina film].[不同退火条件对纳米多孔氧化铝薄膜光致发光的影响]
Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Dec;33(12):3197-201.
9
High-throughput production of LuAG-based highly luminescent thick film scintillators for radiation detection and imaging.高通量制备基于 LuAG 的高发光厚膜闪烁体用于辐射探测和成像。
Sci Rep. 2022 Nov 11;12(1):19319. doi: 10.1038/s41598-022-23839-w.
10
Crystal Structure and Optical Properties of ZnO:Ce Nano Film.ZnO:Ce纳米薄膜的晶体结构与光学性质
Molecules. 2022 Aug 20;27(16):5308. doi: 10.3390/molecules27165308.

本文引用的文献

1
YAG:Ce Transparent Ceramic Phosphors Brighten the Next-Generation Laser-Driven Lighting.钇铝石榴石：铈透明陶瓷荧光粉照亮下一代激光驱动照明。
Adv Mater. 2020 May;32(19):e1907888. doi: 10.1002/adma.201907888. Epub 2020 Mar 29.
2
Electronic and optical properties of a novel fluoroaluminate red phosphor CsNaAlF:Mn with high color purity for white light-emitting diodes.
Dalton Trans. 2019 Sep 7;48(33):12459-12465. doi: 10.1039/c9dt02577d. Epub 2019 Jul 29.
3
A revolution in lighting.照明领域的一场革命。
Nat Mater. 2015 May;14(5):454-8. doi: 10.1038/nmat4270.