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Synthesis and Characterization of High-Entropy-Alloy-Type Layered Telluride BiTe ( = Ag, In, Sn, Pb, Bi).

作者信息

Nakahira Yuki, Shimono Seiya, Goto Yosuke, Miura Akira, Moriyoshi Chikako, Mizuguchi Yoshikazu

机构信息

Department of Physics, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji 192-0397, Japan.

Department of Materials Science and Engineering, National Defense Academy, Kanagawa 239-8686, Japan.

出版信息

Materials (Basel). 2022 Apr 1;15(7):2614. doi: 10.3390/ma15072614.

DOI:10.3390/ma15072614
PMID:35407946
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9000834/
Abstract

Recently, high-entropy alloys (HEAs) and HEA-type compounds have been extensively studied in the fields of material science and engineering. In this article, we report on the synthesis of a layered system BiTe where the site possesses low-, middle-, and high-entropy states. The samples with = Pb, AgPbBi, and AgInSnPbBi were newly synthesized and the crystal structure was examined by synchrotron X-ray diffraction and Rietveld refinement. We found that the -Te2 distance was systematically compressed with decreasing lattice constants, where the configurational entropy of mixing at the site is also systematically increased. The details of structural refinements and the electrical transport property are presented.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/41b74a3986a9/materials-15-02614-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/787613d00057/materials-15-02614-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/275001d30b54/materials-15-02614-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/fa4c9706ba7a/materials-15-02614-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/41b74a3986a9/materials-15-02614-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/787613d00057/materials-15-02614-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/275001d30b54/materials-15-02614-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/fa4c9706ba7a/materials-15-02614-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8bec/9000834/41b74a3986a9/materials-15-02614-g004.jpg

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1
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本文引用的文献

1
Robustness of superconductivity to external pressure in high-entropy-alloy-type metal telluride AgInSnPbBiTe.高熵合金型金属碲化物AgInSnPbBiTe中超导性对外部压力的鲁棒性。
Sci Rep. 2022 May 12;12(1):7789. doi: 10.1038/s41598-022-11862-w.
2
Entropy engineering promotes thermoelectric performance in p-type chalcogenides.熵工程提升了p型硫族化物的热电性能。
Nat Commun. 2021 May 28;12(1):3234. doi: 10.1038/s41467-021-23569-z.
3
High-Entropy van der Waals Materials Formed from Mixed Metal Dichalcogenides, Halides, and Phosphorus Trisulfides.
由混合金属二硫属化物、卤化物和三硫化磷形成的高熵范德华材料。
J Am Chem Soc. 2021 May 12;143(18):7042-7049. doi: 10.1021/jacs.1c01580. Epub 2021 Apr 29.
4
High-entropy-stabilized chalcogenides with high thermoelectric performance.具有高热电性能的高熵稳定硫属化物。
Science. 2021 Feb 19;371(6531):830-834. doi: 10.1126/science.abe1292.
5
High Thermoelectric Performance in the New Cubic Semiconductor AgSnSbSe by High-Entropy Engineering.通过高熵工程在新型立方半导体AgSnSbSe中实现的高热电性能。
J Am Chem Soc. 2020 Sep 2;142(35):15187-15198. doi: 10.1021/jacs.0c07803. Epub 2020 Aug 24.
6
Growth and Characterization of ROBiS High-Entropy Superconducting Single Crystals.ROBiS 高熵超导单晶的生长与表征
ACS Omega. 2020 Jul 1;5(27):16819-16825. doi: 10.1021/acsomega.0c01969. eCollection 2020 Jul 14.
7
An efficient way of increasing the total entropy of mixing in high-entropy-alloy compounds: a case of NaCl-type (Ag,In,Pb,Bi)TeSe (x = 0.0, 0.25, 0.5) superconductors.
Dalton Trans. 2020 Jul 7;49(26):9118-9122. doi: 10.1039/d0dt01880e.
8
Vibrational spectra of PbBiTe, PbBiTe, and PbBiTe topological insulators: temperature-dependent Raman and theoretical insights from DFT simulations.PbBiTe、PbBiTe和PbBiTe拓扑绝缘体的振动光谱:温度相关的拉曼光谱及来自密度泛函理论模拟的理论见解。
Phys Chem Chem Phys. 2019 Jul 10;21(27):15030-15039. doi: 10.1039/c9cp01494b.
9
Data-driven exploration of new pressure-induced superconductivity in PbBiTe.基于数据驱动对PbBiTe中新型压力诱导超导性的探索。
Sci Technol Adv Mater. 2018 Nov 16;19(1):909-916. doi: 10.1080/14686996.2018.1548885. eCollection 2018.
10
Robust zero resistance in a superconducting high-entropy alloy at pressures up to 190 GPa.在高达 190 GPa 的压力下,超导高熵合金中存在稳健的零电阻。
Proc Natl Acad Sci U S A. 2017 Dec 12;114(50):13144-13147. doi: 10.1073/pnas.1716981114. Epub 2017 Nov 28.