Department of Chemical Engineering, B V Raju Institute of Technology, Medak (District), Narsapur, Telangana State, 502313, India.
School of Chemical Engineering, Hanoi University of Science & Technology, Hanoi, Vietnam.
Environ Sci Pollut Res Int. 2023 Feb;30(10):25532-25545. doi: 10.1007/s11356-022-20165-6. Epub 2022 Apr 13.
In this work, preparation of ZIF-8 supported BiFeO photocatalyst by ultrasound cavitation technique was reported. The synthesized materials were characterized using solid UV absorption spectroscopy, Raman Spectroscopy, and SEM. The catalytic function of synthesized photocatalyst under ultraviolet and visible light was examined for the decolourization of Rhodamine-B (Rh-B) dye. To understand the action of the photocatalyst on Rh-B decolorization, the influence of different operating parameters such as wt% of ZIF-8 in composite, catalyst dosage, initial dye concentration, initial solution pH, and source of light was examined. The obtained results show that 40.7 wt% of ZIF-8/BiFeO composite exhibited the highest possible photocatalytic behaviour against decolorization of Rh-B dye. The acidic pH of the solution had shown greater effectiveness in removing Rh-B dye. The tests and study demonstrate that the hybrid ZIF-8/BiFeO has a stronger photocatalytic activity for decolorization of the Rh-B dye relative to the ZIF-8 MOF and BiFeO. The synthesized ZIF-8/BiFeO demonstrated outstanding photocatalytic behaviour in the presence of ultraviolet and visible light towards the removal of Rh-B dye from the aqueous media.
在这项工作中,报道了通过超声空化技术制备 ZIF-8 负载 BiFeO 光催化剂。采用固体紫外吸收光谱、拉曼光谱和 SEM 对合成材料进行了表征。研究了合成光催化剂在紫外光和可见光下对罗丹明 B(Rh-B)染料的脱色作用。为了了解光催化剂对 Rh-B 脱色的作用,考察了不同操作参数的影响,如复合材料中 ZIF-8 的重量百分比、催化剂用量、初始染料浓度、初始溶液 pH 值和光源。结果表明,40.7wt%的 ZIF-8/BiFeO 复合材料对 Rh-B 染料的脱色表现出最高的光催化性能。溶液的酸性 pH 值在去除 Rh-B 染料方面表现出更高的效果。实验和研究表明,相对于 ZIF-8 MOF 和 BiFeO,杂化 ZIF-8/BiFeO 对 Rh-B 染料的脱色具有更强的光催化活性。在紫外光和可见光存在的情况下,合成的 ZIF-8/BiFeO 对从水介质中去除 Rh-B 染料表现出优异的光催化性能。