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用于高效光催化降解有机染料的CdZnS@金属有机框架ZIF-8的开发与合成

The Development and Synthesis of a CdZnS @Metal-Organic Framework ZIF-8 for the Highly Efficient Photocatalytic Degradation of Organic Dyes.

作者信息

Hong Liu, Cao Jiaming, Zhang Wenlong, Jiang Tao, Pan Guohao, Wu Yun

机构信息

School of Energy Materials and Chemical Engineering, Hefei University, Hefei 230601, China.

出版信息

Molecules. 2023 Dec 2;28(23):7904. doi: 10.3390/molecules28237904.

Abstract

The development of photocatalysts for organic degradation is a hot research topic. In this study, CdZnS was selected as the carrier, and ZIF-8 was combined with it to explore the photocatalytic performance of the composite. In addition, the compound material, CdZnS@ZIF-8, was used as a photocatalyst for the decomposition of methylene blue dye, and the performance of pure CdZnS and pure ZIF-8 was compared. The photocatalytic efficiency of CdZnS@ZIF-8 was significantly higher than that of the other two. In the experimental reaction, the amount of catalyst was 0.04 g, the pH value was 7, the initial concentration of methylene blue aqueous solution was 20 mg/L, and the degradation of methylene blue in 50 mL aqueous solution could reach 99.5% under visible light irradiation for 90 min, showing excellent photocatalytic efficiency in the visible light range. It demonstrated excellent photocatalytic function in the visible light region, and the electron transfer phenomenon at the interface occurred in the het-junction and the separation of the photo-generating electron-hole as an electron acceptor of ZIF-8 further promoted the photocatalytic effect.

摘要

用于有机降解的光催化剂的开发是一个热门研究课题。在本研究中,选择CdZnS作为载体,并将ZIF-8与之复合以探究该复合材料的光催化性能。此外,将复合材料CdZnS@ZIF-8用作光催化剂来分解亚甲基蓝染料,并比较了纯CdZnS和纯ZIF-8的性能。CdZnS@ZIF-8的光催化效率明显高于其他两者。在实验反应中,催化剂用量为0.04 g,pH值为7,亚甲基蓝水溶液的初始浓度为20 mg/L,在可见光照射90 min下,50 mL水溶液中亚甲基蓝的降解率可达99.5%,在可见光范围内显示出优异的光催化效率。它在可见光区域表现出优异的光催化功能,并且在异质结处发生了界面电子转移现象,作为电子受体的ZIF-8使光生电子-空穴分离,进一步促进了光催化效果。

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