Charles R Malcolm, Brewster Timothy P
Department of Chemistry, The University of Memphis, 3744 Walker Ave., Smith Chemistry Building, Memphis, TN 38152, United States.
Coord Chem Rev. 2021 Apr;433. doi: 10.1016/j.ccr.2020.213765. Epub 2021 Feb 7.
The field of heterobimetallic chemistry has rapidly expanded over the last decade. In addition to their interesting structural features, heterobimetallic structures have been found to facilitate a range of stoichiometric bond activations and catalytic processes. The accompanying review summarizes advances in this area since January of 2010. The review encompasses well-characterized heterobimetallic complexes, with a particular focus on mechanistic details surrounding their reactivity applications.
在过去十年中，异双金属化学领域迅速发展。除了具有有趣的结构特征外，人们还发现异双金属结构有助于一系列化学计量的键活化和催化过程。随附的综述总结了自2010年1月以来该领域的进展。该综述涵盖了表征明确的异双金属配合物，特别关注围绕其反应性应用的机理细节。
