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基于废弃食用油的蜡的合成与性能

Synthesis and properties of wax based on waste cooking oil.

作者信息

Liu Yan, Liu Meng-Yu, Qi Ying-Xi, Jin Xin-Yan, Xu Han-Rui, Chen Yu-Xin, Chen Shuo-Ping, Su He-Ping

机构信息

College of Materials Science and Engineering, Guilin University of Technology China.

College of Science, Guilin University of Technology China.

出版信息

RSC Adv. 2022 Jan 25;12(6):3365-3371. doi: 10.1039/d1ra08874b. eCollection 2022 Jan 24.

Abstract

In this work, a cost-effective wax was synthesized from waste cooking oil (WCO), and its properties including melting point, color, hardness, combustion performance and micro-morphology were tested and analyzed. The obtained results showed that the epoxy waste cooking oil had lighter color, higher melting point and hardness than that of original WCO, which could be used as wax. Moreover, introducing stearic acid further improved the performances of WCO-based wax. The WCO-based wax made of epoxy waste cooking oil and stearic acid (containing ≥50 wt% stearic acid) displayed a relatively high melting point (≥46 °C), light color (Lovibond color code ≤ 16.1, ≤ 2.3), good hardness (needle penetration index ≤2.95 mm) and long combustion time (≥227 min), and could achieve the required national standard and be used as a substitute for the commercially available soybean wax. Together with many additional benefits such as low synthesis cost, mild reaction conditions, convenient synthesis route, and no secondary pollution, producing wax based on WCO could provide a new path for WCO recycling in economically trailing regions.

摘要

在这项工作中,由废食用油(WCO)合成了一种具有成本效益的蜡,并对其熔点、颜色、硬度、燃烧性能和微观形态等性质进行了测试和分析。所得结果表明,环氧废食用油比原始WCO颜色更浅、熔点和硬度更高,可作为蜡使用。此外,引入硬脂酸进一步改善了基于WCO的蜡的性能。由环氧废食用油和硬脂酸制成的基于WCO的蜡(含≥50 wt%硬脂酸)具有相对较高的熔点(≥46 °C)、浅色(罗维朋颜色代码≤16.1,≤2.3)、良好的硬度(针入度指数≤2.95 mm)和较长的燃烧时间(≥227分钟),能够达到国家要求标准,并可作为市售大豆蜡的替代品。基于WCO生产蜡具有合成成本低、反应条件温和、合成路线简便且无二次污染等诸多额外优势,可为经济落后地区的WCO回收利用提供一条新途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52c4/8979279/c23782058cb9/d1ra08874b-f1.jpg

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