Wang Guan-E, Luo ShaoZhen, Di Tuo, Fu ZhiHua, Xu Gang
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), 155 Yangqiao Road West, Fuzhou, Fujian, 350002, China.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, P. R. China.
Angew Chem Int Ed Engl. 2022 Jul 4;61(27):e202203151. doi: 10.1002/anie.202203151. Epub 2022 May 20.
The modification of inorganic two-dimensional (2D) materials with organic functional motifs is in high demand for the optimization of their properties, but it is still a daunting challenge. Organic metal chalcogenides (OMCs) are a type of newly emerging 2D materials, with metal chalcogenide layers covalently anchored by long-range ordered organic functional motifs, these materials are extremely desirable but impossible to realize by traditional methods. Both the inorganic layer and organic functional motifs of OMCs are highly designable and thus provide this type of 2D materials with enormous variety in terms of their structure and properties. This Minireview aims to review the latest developments in OMCs and their bulk precursors. Firstly, the structure types of the bulk precursors for OMCs are introduced. Second, the synthesis and applications of OMC 2D materials in photoelectricity, catalysis, sensors, and energy transfer are explored. Finally, the challenges and perspectives for future research on OMCs are discussed.
用有机功能基团修饰无机二维（2D）材料对于优化其性能有很高的需求，但这仍然是一项艰巨的挑战。有机金属硫族化合物（OMC）是一类新兴的二维材料，其金属硫族化合物层由长程有序的有机功能基团共价锚定，这类材料极具吸引力，但用传统方法无法实现。OMC的无机层和有机功能基团都具有高度可设计性，因此赋予了这类二维材料在结构和性能方面的巨大多样性。本综述旨在回顾OMC及其块状前驱体的最新进展。首先，介绍了OMC块状前驱体的结构类型。其次，探讨了OMC二维材料在光电、催化、传感器和能量转移方面的合成与应用。最后，讨论了OMC未来研究面临的挑战和前景。
