Moreno-Juez Jaime, Caneda-Martínez Laura, Vigil de la Villa Raquel, Vegas Iñigo, Frías Moisés
Tecnalia, Basque Research and Technology Alliance (BRTA), Astondo Bidea, Edificio 700, Parque Tecnológico de Bizkaia, 48160 Derio, Spain.
Eduardo Torroja Institute for Construction Science (IETcc-CSIC), 28033 Madrid, Spain.
Materials (Basel). 2022 Apr 16;15(8):2921. doi: 10.3390/ma15082921.
In recent years, the development of ternary cements has become a priority research line for obtaining cements with a lower carbon footprint, with the goal to contribute to achieve climate neutrality by 2050. This study compared ordinary Portland cement (OPC) durability to the performance of ternary cements bearing OPC plus 7% of a 2:1 binary blend of either calcareous (Hc) or siliceous (Hs) concrete waste fines and shatterproof glass. Durability was measured further to the existing legislation for testing concrete water absorption, effective porosity, pressurized water absorption and resistance to chlorides and CO. The experimental findings showed that the 7% blended mortars performed better than the reference cement in terms of total and effective porosity, but they absorbed more pressurized water. They also exhibited lower CO resistance, particularly in the calcareous blend, likely due to its higher porosity. Including the binary blend of CDW enhanced chloride resistance with diffusion coefficients of 2.9 × 10 m s (calcareous fines-glass, 7%Hc-G) and 1.5 × 10 m s (siliceous fines-glass, 7%Hs-G) compared to the reference cement's 4.3 × 10 m s. The siliceous fines-glass blend out-performed the calcareous blend in all the durability tests. As the mortars with and without CDW (construction and demolition waste) performed to similar standards overall, the former were deemed viable for the manufacture of future eco-efficient cements.
近年来,三元水泥的开发已成为获得低碳足迹水泥的优先研究方向,目标是为到2050年实现气候中和做出贡献。本研究将普通硅酸盐水泥(OPC)的耐久性与含有OPC加7%钙质(Hc)或硅质(Hs)混凝土废细粉与防弹玻璃2:1二元混合物的三元水泥的性能进行了比较。根据现有测试混凝土吸水率、有效孔隙率、加压吸水率以及抗氯化物和抗CO性能的法规对耐久性进行了测量。实验结果表明,7%的混合砂浆在总孔隙率和有效孔隙率方面比参考水泥表现更好,但它们吸收了更多的加压水。它们还表现出较低的抗CO性能,特别是在钙质混合物中,这可能是由于其较高的孔隙率。与参考水泥的4.3×10⁻¹²m²/s相比,加入CDW(建筑和拆除废物)二元混合物提高了抗氯化物性能,扩散系数分别为2.9×10⁻¹²m²/s(钙质细粉 - 玻璃,7%Hc - G)和1.5×10⁻¹²m²/s(硅质细粉 - 玻璃,7%Hs - G)。在所有耐久性测试中,硅质细粉 - 玻璃混合物的性能优于钙质混合物。由于含和不含CDW的砂浆总体表现达到相似标准,因此前者被认为可用于制造未来的生态高效水泥。