Division of coal spontaneous combustion stages and selection of indicator gases.

Investigating the division of coal spontaneous combustion stages and the selection of indicator gases is significant to the safe production of coal mines. In this study, the characteristic temperature of coal spontaneous combustion, the generation law of indicator gases, the combustion process, and the division of the combustion stages of coal samples taken from Hongqingliang (HQL) and Dayan (DY) mines were investigated using thermogravimetric analysis experiment, indicator gas detection experiment, and coal oxidation spontaneous combustion experiment. The results of the thermogravimetric analysis experiment showed that the pyrolysis temperatures of the HQL and DY coals were 115.76°C and 131.80°C, and the ignition temperatures were 337.74°C and 360.18°C, respectively. The indicator gas detection results showed that the first-appearance temperature of C2H4 was 85°C for the HQL and DY coals, whereas the first-appearance temperature of C2H6 varied: 115°C for the HQL coal and 130°C for the DY coal. The first-appearance temperatures of C2H2 were 180°C and 195°C for the HQL and DY coals, respectively. The experiments on coal oxidation spontaneous combustion showed that the spontaneous combustion period of the HQL and DY coals were 35.45 and 42.3 days, respectively. The heating process during combustion could be divided into four stages: a latent period of spontaneous combustion, a slow spontaneous heating period, an accelerated spontaneous heating period, and a period of combustion. The critical temperature of each stage showed a good correlation with the incipient temperature of the indicator gases, namely C2H2, C2H4, and C2H6, and the appearance of the above gases can be used to characterize the degree of spontaneous combustion of coal.