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通过液相等离子体合成金属有机框架以增加还原态金属离子并提高水稳定性。

Synthesis of a metal-organic framework by plasma in liquid to increase reduced metal ions and enhance water stability.

作者信息

Kanno Moriyuki, Kitao Takashi, Ito Tsuyohito, Terashima Kazuo

机构信息

Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo 5-1-5 Kashiwanoha Kashiwa Chiba 277-8561 Japan

出版信息

RSC Adv. 2021 Jun 28;11(37):22756-22760. doi: 10.1039/d1ra00942g. eCollection 2021 Jun 25.

DOI:10.1039/d1ra00942g
PMID:35480462
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9034360/
Abstract

Synthesis of a metal-organic framework by plasma in liquid was demonstrated with HKUST-1 as an example. HKUST-1 synthesized by this method contains a higher amount of monovalent copper ions than that synthesized by other conventional methods. The enhanced water stability was also confirmed.

摘要

以HKUST-1为例，展示了通过液相等离子体合成金属有机框架。用这种方法合成的HKUST-1比通过其他传统方法合成的含有更多的一价铜离子。还证实了其水稳定性增强。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/ce6c7681df76/d1ra00942g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/8da272820013/d1ra00942g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/ffd5ca6efa14/d1ra00942g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/f1c68d0a2c47/d1ra00942g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/924d96af5c06/d1ra00942g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/ce6c7681df76/d1ra00942g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/8da272820013/d1ra00942g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/ffd5ca6efa14/d1ra00942g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/f1c68d0a2c47/d1ra00942g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/924d96af5c06/d1ra00942g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56f7/9034360/ce6c7681df76/d1ra00942g-f5.jpg

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Applications of Plasma-Liquid Systems: A Review.等离子体-液体系统的应用：综述
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Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes.具有非常规氮杂环卡宾的二配位铜（I）配合物的高效光致发光和电致发光
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Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies.面向新型多金属铜（I）发光组装体的自适应配位驱动超分子合成
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