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基于CFBCA的地聚合物-砒砂岩水泥复合土的强度及微观机理分析

Strength and microscopic mechanism analysis of CFBCA-based geopolymer-Pisha sandstone cement composite soil.

作者信息

Zhu Jiahui, Li Xiaoli

机构信息

College of Water Conservancy and Civil Engineering, Inner Mongolia Agricultural University, Hohhot, 010018, China.

出版信息

Environ Sci Pollut Res Int. 2022 Sep;29(43):65197-65210. doi: 10.1007/s11356-022-20427-3. Epub 2022 Apr 29.

Abstract

Solidification of soil mass by geopolymer is a novel technology that can be used to prevent soil and water loss in the Pisha sandstone area of the middle reaches of the Yellow River. In this paper, to realize the effective utilization of a large number of loose Pisha sandstone and circulating fluidized bed combustion fly ash by adding combustion fly ash into Pisha sandstone cement-soil by alkali excitation, we prepared CFBCA-based geopolymer-Pisha sandstone cement composite soil, which is often used in agricultural engineering. The results show that the content of (C, N)-A-S-H gel in composite soil is affected by alkali equivalent and alkali excitation temperature, while the content is the main factor affecting the strength of composite soil. However, (C, N)-A-S-H gel will gradually transform into chabazite (gmelinite) crystal in a high-alkali environment, which will eventually lead to expansion and cracking occurring in the samples. When the alkali excitation temperature is 20 °C, and the alkali equivalent is 5%, the CFBCA-based geopolymer-Pisha sandstone cement composite soil is the optimal physicochemical reaction condition. At this time, the strength of the composite soil is 6.85 MPa; the porosity is 23.88%; and the proportion of internal micro-pores is 16.32%. The results of this study can provide a theoretical basis for the practical application of CFBCA-based geopolymer-Pisha sandstone cement composite soil, and also provide a scientific basis for the local resource utilization of Pisha sandstone and bed combustion fly ash.

摘要

地质聚合物固化土体是一项可用于黄河中游砒砂岩地区防治水土流失的新技术。本文通过碱激发将循环流化床燃烧粉煤灰添加到砒砂岩水泥土中,以实现大量松散砒砂岩和循环流化床燃烧粉煤灰的有效利用,制备了常用于农业工程的基于CFBCA的地质聚合物-砒砂岩水泥复合土。结果表明,复合土中(C,N)-A-S-H凝胶的含量受碱当量和碱激发温度的影响,而该含量是影响复合土强度的主要因素。然而,(C,N)-A-S-H凝胶在高碱环境下会逐渐转变为菱沸石(片沸石)晶体,最终导致试样出现膨胀开裂现象。当碱激发温度为20℃、碱当量为5%时,基于CFBCA的地质聚合物-砒砂岩水泥复合土处于最佳物理化学反应条件。此时,复合土强度为6.85MPa;孔隙率为23.88%;内部微孔比例为16.32%。本研究结果可为基于CFBCA的地质聚合物-砒砂岩水泥复合土的实际应用提供理论依据,也可为砒砂岩和床燃烧粉煤灰的当地资源利用提供科学依据。

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