铑催化水溶性二硫化物与四烷基次磷酸酯在水中的磷酸化反应。
Rhodium-catalyzed phosphorylation reaction of water-soluble disulfides using hypodiphosphoric acid tetraalkyl esters in water.
作者信息
Arisawa Mieko, Fukumoto Kohei, Yamaguchi Masahiko
机构信息
Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University Aoba Sendai 980-8578 Japan
出版信息
RSC Adv. 2020 Apr 6;10(23):13820-13823. doi: 10.1039/d0ra02377a. eCollection 2020 Apr 1.
Abstract
RhCl catalyzed the exchange reaction of disulfides and hypodiphosphoric acid tetraalkyl esters in water under homogeneous conditions, which indicated the hypodiphosphoric acid tetraalkyl esters to be novel and efficient phosphorylation reagents in water. The reaction was used in the phosphorylation of unprotected glutathione disulfide.
摘要
在均相条件下，RhCl催化了水中二硫化物与次磷酸四烷基酯的交换反应，这表明次磷酸四烷基酯是水中新型且高效的磷酸化试剂。该反应被用于未保护的谷胱甘肽二硫化物的磷酸化反应。
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