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通过绿色方法合成的rGO/Pt纳米复合材料的实时监测光催化活性和电化学性能。

Real-time monitored photocatalytic activity and electrochemical performance of an rGO/Pt nanocomposite synthesized a green approach.

作者信息

Kasturi Satish, Torati Sri Ramulu, Eom Yun Ji, Ahmad Syafiq, Lee Byong-June, Yu Jong-Sung, Kim CheolGi

机构信息

Department of Emerging Materials Science, DGIST Daegu-42988 Republic of Korea

Department of Energy Science and Engineering, DGIST Daegu-42988 Republic of Korea.

出版信息

RSC Adv. 2020 Apr 3;10(23):13722-13731. doi: 10.1039/d0ra00541j. eCollection 2020 Apr 1.

Abstract

Herein, we have reported the real-time photodegradation of methylene blue (MB), an organic pollutant, in the presence of sunlight at an ambient temperature using a platinum-decorated reduced graphene oxide (rGO/Pt) nanocomposite. The photocatalyst was prepared a simple, one-pot and green approach with the simultaneous reduction of GO and Pt using aqueous honey as a reducing agent. Moreover, the honey not only simultaneously reduced Pt ions and GO but also played a key role in the growth and dispersion of Pt nanoparticles on the surface of rGO. Various rGO/Pt nanocomposites with different percentages of Pt nanoparticles loaded on rGO were obtained by tuning the concentration of the Pt source. The high percentage of Pt nanoparticles with an average size of 2.5 nm dispersed on rGO has shown excellent electrochemical performance. The photocatalytic activity of the rGO/Pt composite was enhanced by increasing the weight percent of the Pt particles on rGO, which led to the formation of a highly efficient photocatalyst. The optimized photocatalyst exhibited remarkable photocatalytic activity and degraded 98% MB in 180 minutes; thus, it can be used for industrial and environmental applications.

摘要

在此,我们报道了使用铂修饰的还原氧化石墨烯(rGO/Pt)纳米复合材料,在环境温度下于阳光照射下对有机污染物亚甲基蓝(MB)进行实时光降解。该光催化剂采用一种简单的一锅法绿色方法制备,使用水性蜂蜜作为还原剂同时还原氧化石墨烯(GO)和铂。此外,蜂蜜不仅同时还原铂离子和氧化石墨烯,还在铂纳米颗粒在还原氧化石墨烯表面的生长和分散中起关键作用。通过调节铂源的浓度,获得了不同百分比的铂纳米颗粒负载在还原氧化石墨烯上的各种rGO/Pt纳米复合材料。平均尺寸为2.5 nm的高百分比铂纳米颗粒分散在还原氧化石墨烯上,表现出优异的电化学性能。rGO/Pt复合材料的光催化活性通过增加铂颗粒在还原氧化石墨烯上的重量百分比而增强,这导致形成了一种高效的光催化剂。优化后的光催化剂表现出显著的光催化活性,在180分钟内降解了98%的亚甲基蓝;因此,它可用于工业和环境应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f3d7/9051565/01895329f575/d0ra00541j-f1.jpg

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