Defect-induced nucleation and epitaxial growth of a MOF-derived hierarchical MoC@Co architecture for an efficient hydrogen evolution reaction.

The 3D hierarchical structure in catalysts not only the preserves intrinsic characteristics of each component, but also achieves increased specific surface area and active sites for the hydrogen evolution reaction (HER). Herein, we report a new strategy to synthesize efficient 3D hierarchical catalysts composed of MoC nanosheets and Co nanoparticles (H-MoC@Co). It was realized by using raw materials, defect-rich MoO , Co(NO)·6HO and 2-methylimidazole, to design Mo/Co bimetallic metal-organic frameworks (BMOFs), followed by pyrolysis at 800 °C. The defects in MoO induced preferential nucleation and growth of the BMOFs so that they can ensure the construction of a stable 3D hierarchical structure. MoC and Co have a synergistic effect in improving the HER providing large surface areas (351.5 m g), more active sites and optimizing charge transfer. It can achieve 10 mA cm at low overpotential over a wide pH range (144 mV in 0.5 M HSO and 103 mV in 1.0 M KOH) and the properties can be well maintained in both acid and alkaline electrolyte after 2000 cycles. The hierarchical catalyst contains no noble metal, can be synthesized on a large scale and recycled by magnetic stirring, demonstrating great potential in water splitting, wastewater treatment, dye adsorption and other fields.