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一维无限银炔基组装体[Ag(C≡C Bu)(CFCOO)(CHCN)]：合成、晶体结构及性质

A one-dimensional infinite silver alkynyl assembly [Ag(C[triple bond, length as m-dash]C Bu)(CFCOO)(CHCN)] : synthesis, crystal structure and properties.

作者信息

Shi Ju-Feng, Chen Zhi-Jin, Zhang Liu-Jie, Zhou Kun, Ji Jiu-Yu, Bi Yan-Feng

机构信息

School of Chemistry and Materials Science, Liaoning Shihua University Fushun Liaoning 113001 China

出版信息

RSC Adv. 2020 Apr 22;10(27):16045-16049. doi: 10.1039/d0ra01703e. eCollection 2020 Apr 21.

DOI:10.1039/d0ra01703e
PMID:35493660
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9052916/
Abstract

A high-yield silver alkynyl assembly [Ag(C[triple bond, length as m-dash]C Bu)(CFCOO)(CHCN)] (1) constructed from [AgC[triple bond, length as m-dash]C Bu] ligand, CFCOOAg and CHCN auxiliary ligands with a one-dimensional infinite chain structure has been obtained in one pot. Compound 1 has been well-defined and characterized. The photocurrent properties and the temperature-sensitive luminescent properties of 1 have been investigated.

摘要

通过一锅法得到了一种高产率的银炔基组装体[Ag(C≡C Bu)(CFCOO)(CHCN)] (1)，它由[AgC≡C Bu]配体、CFCOOAg和CHCN辅助配体构建而成，具有一维无限链结构。化合物1已得到明确表征。对其光电流性质和温度敏感发光性质进行了研究。

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