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使用3D打印膜装置分离多组分多相液体混合物。

Separating a multicomponent and multiphase liquid mixture with a 3D-printed membrane device.

作者信息

Yang Fan, Wang Bingchen, Baimoldina Aigerim, Song Yihan, Altemose Patrick, Kowall Cliff, Li Lei

机构信息

Department of Chemical & Petroleum Engineering, University of Pittsburgh Pennsylvania 15261 USA

出版信息

RSC Adv. 2021 Dec 16;11(63):40033-40039. doi: 10.1039/d1ra08623e. eCollection 2021 Dec 13.

DOI:10.1039/d1ra08623e
PMID:35494154
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9044559/
Abstract

The separation of multicomponent and multiphase liquid mixtures is critical in many important applications, , wastewater treatment. While conventional technologies have been utilized in the separation, it usually takes many steps, resulting in high cost and energy consumption. Here we have demonstrated that, using a 3D-printed membrane device with multiple selectivity, a multicomponent and multiphase liquid mixture can be separated in a much more efficient way. The water-benzene-heptane mixture has been successfully separated with a 3D-printed "box", which has a supported ionic liquid membrane (SILM) on the side wall and a hydrogel-coated hydrophilic/oleophobic membrane on the bottom. The water and oil (, benzene/heptane) are separated by the hydrogel-coated hydrophilic/oleophobic membrane. Then the benzene is separated from heptane with the SILM. To further increase the separation throughput, the structure of the 3D-printed "box" has been optimized to increase the total surface area of SILM. Our results suggest that 3D-printed membrane device with multiple selectivity is promising in the separation of multicomponent and multiphase liquid mixtures.

摘要

多组分多相液体混合物的分离在许多重要应用中至关重要,例如废水处理。虽然传统技术已用于分离,但通常需要多个步骤,导致成本高和能耗大。在此我们证明,使用具有多重选择性的3D打印膜装置,可以更高效地分离多组分多相液体混合物。水 - 苯 - 庚烷混合物已通过一个3D打印的“盒子”成功分离,该“盒子”的侧壁上有支撑离子液体膜(SILM),底部有涂覆水凝胶的亲水/疏油膜。水和油(如苯/庚烷)通过涂覆水凝胶的亲水/疏油膜分离。然后用SILM将苯与庚烷分离。为了进一步提高分离通量,对3D打印“盒子”的结构进行了优化,以增加SILM的总表面积。我们的结果表明,具有多重选择性的3D打印膜装置在多组分多相液体混合物的分离中具有前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/c96a5aac8d77/d1ra08623e-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/825dc46b9d06/d1ra08623e-f1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/719483adf78d/d1ra08623e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/36494929bffa/d1ra08623e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/9e46e24235c1/d1ra08623e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/1dce27cce320/d1ra08623e-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/ee850c92cef7/d1ra08623e-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/c96a5aac8d77/d1ra08623e-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/825dc46b9d06/d1ra08623e-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/9a956b79da3d/d1ra08623e-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/653b7b5973e4/d1ra08623e-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/719483adf78d/d1ra08623e-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/36494929bffa/d1ra08623e-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/9e46e24235c1/d1ra08623e-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/1dce27cce320/d1ra08623e-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/ee850c92cef7/d1ra08623e-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3805/9044559/c96a5aac8d77/d1ra08623e-f9.jpg

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